Influence of salts on hydrophobically end-capped polyethylene oxides in aqueous solution

被引:5
作者
Beaudoin, E [1 ]
Gourier, C [1 ]
Lapp, A [1 ]
François, J [1 ]
机构
[1] CEA Saclay, Lab Leon Brillouin, F-91191 Gif Sur Yvette, France
关键词
D O I
10.1002/masy.19991460123
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The influence of four different salts (NaCl, KBr, CaCl2 and MgCl2, on the associative behaviour of poly(ethylene oxide) (POE with M=32000g/mol) hydrophobically end-capped with hexadecyl groups in aqueous solutions was investigated. Phase diagrams were obtained, structural properties were established by small angle neutron scattering (SANS) measurements and studies on the viscoelastic properties of the solutions were performed by low-shear viscosity and dynamic stress experiments. The influence of the four salts is compared as well as the difference of the interactions obtained with and without salts.
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收藏
页码:171 / 177
页数:7
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