Application of Kinetic, Isotherm, and Thermodynamic Models for Atrazine Adsorption on Nanoporous Polymeric Adsorbents

被引:6
作者
Ipek, Idil Yilmaz [1 ]
机构
[1] Ege Univ, Dept Chem Engn, Fac Engn, TR-35100 Izmir, Turkey
关键词
adsorption; thermodynamics; atrazine; kinetics; polymeric adsorbents; ACTIVATED CARBON; AQUEOUS-SOLUTION; ORGANIC-MATTER; WASTE-WATER; REMOVAL; EQUILIBRIUM; SORPTION; PESTICIDES;
D O I
10.1080/01496395.2014.915415
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Adsorption of atrazine on nanoporous polymeric adsorbents, PAD 400 and PAD 610, was investigated. The effect of particle size, pH, ionic strength, and temperature along with kinetic, equilibrium, and thermodynamic studies reveal the efficiency of PAD 400 with a higher adsorption capacity than PAD 610. The equilibrium data obey the Freundlich isotherm and the kinetic data were well described by the pseudo-second-order model. Spontaneous, endothermic, and random characteristics of the process were confirmed by thermodynamic analysis.
引用
收藏
页码:2358 / 2365
页数:8
相关论文
共 39 条
[11]   Piperidine-functionalized supports sequester atrazine from solution [J].
Hollink, E ;
Tichy, SE ;
Simanek, EE .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2005, 44 (06) :1634-1639
[12]   Photolytic and photocatalytic degradation of atrazine in the presence of activated carbon [J].
Jain, Seema ;
Yamgar, Ramesh ;
Jayarama, R. V. .
CHEMICAL ENGINEERING JOURNAL, 2009, 148 (2-3) :342-347
[13]   Adsorption and isothermal models of atrazine by zeolite prepared from Egyptian kaolin [J].
Jamil, Tarek S. ;
Gad-Allah, Tarek A. ;
Ibrahim, Hanan S. ;
Saleh, Tamer S. .
SOLID STATE SCIENCES, 2011, 13 (01) :198-203
[14]   Kinetics, equilibrium and thermodynamic studies on biosorption of hexavalent chromium by dead fungal biomass of marine Aspergillus niger [J].
Khambhaty, Yasmin ;
Mody, Kalpana ;
Basha, Shaik ;
Jha, Bhavanath .
CHEMICAL ENGINEERING JOURNAL, 2009, 145 (03) :489-495
[15]   Adsorption of atrazine from aqueous electrolyte solutions on humic acid and silica [J].
Kovaios, Ilias D. ;
Paraskeva, Christakis A. ;
Koutsoukos, Petros G. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2011, 356 (01) :277-285
[16]   Environmental friendly technology for the removal of pharmaceutical contaminants from wastewaters using modified chitosan adsorbents [J].
Kyzas, George Z. ;
Kostoglou, Margaritis ;
Lazaridis, Nikolaos K. ;
Lambropoulou, Dimitra A. ;
Bikiaris, Dimitrios N. .
CHEMICAL ENGINEERING JOURNAL, 2013, 222 :248-258
[17]   Development of an ELISA procedure to study sorption of atrazine onto a sewage sludge-amended luvisol soil [J].
Lima, Diana L. D. ;
Silva, Carla Patricia ;
Schneider, Rudolf J. ;
Esteves, Valdemar I. .
TALANTA, 2011, 85 (03) :1494-1499
[18]   Adsorption isotherm, kinetic and mechanism studies of some substituted phenols on activated carbon fibers [J].
Liu, Qing-Song ;
Zheng, Tong ;
Wang, Peng ;
Jiang, Ji-Ping ;
Li, Nan .
CHEMICAL ENGINEERING JOURNAL, 2010, 157 (2-3) :348-356
[19]   Sorption of atrazine onto humic acids (HAs) coated nanoparticles [J].
Lu, Jiajuan ;
Li, Ying ;
Yan, Xiaomin ;
Shi, Baoyou ;
Wang, Dongsheng ;
Tang, Hongxiao .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 347 (1-3) :90-96
[20]   Atrazine removal by covalent bonding to piperazine functionalized PolyHIPEs [J].
Pulko, Irena ;
Kolar, Mitja ;
Krajnc, Peter .
SCIENCE OF THE TOTAL ENVIRONMENT, 2007, 386 (1-3) :114-123