Application of Kinetic, Isotherm, and Thermodynamic Models for Atrazine Adsorption on Nanoporous Polymeric Adsorbents

被引:6
作者
Ipek, Idil Yilmaz [1 ]
机构
[1] Ege Univ, Dept Chem Engn, Fac Engn, TR-35100 Izmir, Turkey
关键词
adsorption; thermodynamics; atrazine; kinetics; polymeric adsorbents; ACTIVATED CARBON; AQUEOUS-SOLUTION; ORGANIC-MATTER; WASTE-WATER; REMOVAL; EQUILIBRIUM; SORPTION; PESTICIDES;
D O I
10.1080/01496395.2014.915415
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Adsorption of atrazine on nanoporous polymeric adsorbents, PAD 400 and PAD 610, was investigated. The effect of particle size, pH, ionic strength, and temperature along with kinetic, equilibrium, and thermodynamic studies reveal the efficiency of PAD 400 with a higher adsorption capacity than PAD 610. The equilibrium data obey the Freundlich isotherm and the kinetic data were well described by the pseudo-second-order model. Spontaneous, endothermic, and random characteristics of the process were confirmed by thermodynamic analysis.
引用
收藏
页码:2358 / 2365
页数:8
相关论文
共 39 条
[1]   Atrazine removal using adsorption and electrochemical regeneration [J].
Brown, NW ;
Roberts, EPL ;
Chasiotis, A ;
Cherdron, T ;
Sanghrajka, N .
WATER RESEARCH, 2004, 38 (13) :3067-3074
[2]   Activated carbon/iron oxide composites for the removal of atrazine from aqueous medium [J].
Castro, Cinthia S. ;
Guerreiro, Mario C. ;
Goncalves, Maraisa ;
Oliveira, Luiz C. A. ;
Anastacio, Alexandre S. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 164 (2-3) :609-614
[3]   Adsorption kinetics, isotherms and thermodynamics of atrazine on surface oxidized multiwalled carbon nanotubes [J].
Chen, Guang-Cai ;
Shan, Xiao-Quan ;
Zhou, Yi-Quan ;
Shen, Xiu-e ;
Huang, Hong-Lin ;
Khan, Shahamat U. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 169 (1-3) :912-918
[4]   Oxidative decomposition of atrazine in water in the presence of hydrogen peroxide using an innovative microwave photochemical reactor [J].
Chen, Huilun ;
Bramanti, Emilia ;
Longo, Iginio ;
Onor, Massimo ;
Ferrari, Carlo .
JOURNAL OF HAZARDOUS MATERIALS, 2011, 186 (2-3) :1808-1815
[5]   Preparation and characterization of a lipoid adsorption material and its atrazine removal performance [J].
Chen, Zhiqiang ;
Wen, Qinxue ;
Lian, Jiaxiang ;
Ren, Nanqi .
JOURNAL OF ENVIRONMENTAL SCIENCES, 2011, 23 (08) :1293-1298
[6]   Adsorption of Methylene Blue onto activated carbon produced from steam activated bituminous coal: A study of equilibrium adsorption isotherm [J].
El Qada, Emad N. ;
Allen, Stephen J. ;
Walker, Gavin M. .
CHEMICAL ENGINEERING JOURNAL, 2006, 124 (1-3) :103-110
[7]   Insights into the modeling of adsorption isotherm systems [J].
Foo, K. Y. ;
Hameed, B. H. .
CHEMICAL ENGINEERING JOURNAL, 2010, 156 (01) :2-10
[8]   Pesticides removal from waste water by activated carbon prepared from waste rubber tire [J].
Gupta, V. K. ;
Gupta, Bina ;
Rastogi, Arshi ;
Agarwal, Shilpi ;
Nayak, Arunima .
WATER RESEARCH, 2011, 45 (13) :4047-4055
[9]   Modeling of adsorption isotherms of phenol and chlorophenols onto granular activated carbon - Part I. Two-parameter models and equations allowing determination of thermodynamic parameters [J].
Hamdaoui, Oualid ;
Naffrechoux, Emmanuel .
JOURNAL OF HAZARDOUS MATERIALS, 2007, 147 (1-2) :381-394
[10]   Adsorption isotherm, kinetic modeling and mechanism of 2,4,6-trichlorophenol on coconut husk-based activated carbon [J].
Hameed, B. H. ;
Tan, I. A. W. ;
Ahmad, A. L. .
CHEMICAL ENGINEERING JOURNAL, 2008, 144 (02) :235-244