Monodispersed Pd clusters generated in situ by their own reductive support for high activity and stability in cross-coupling reactions

被引:54
作者
Li, Ping [1 ]
Huang, Pei-Pei [1 ]
Wei, Fang-Fang [1 ]
Sun, Yong-Bin [1 ]
Cao, Chang-Yan [1 ]
Song, Wei-Guo [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, BNLMS, CAS Key Lab Mol Nanostruct & Nanotechnol, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
PALLADIUM NANOPARTICLES; SUZUKI-MIYAURA; AQUEOUS-MEDIA; REUSABLE CATALYST; CASCADE REACTIONS; EFFICIENT; HECK; NANOCRYSTALS; SONOGASHIRA; OXIDATION;
D O I
10.1039/c4ta01811g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Uniform 3D flower-like hierarchical-structured CoAl-LDH spheres were prepared via a simple one-pot surfactant-free solvothermal method. Monodispersed tiny Pd nanoclusters (about 2 nm) were loaded on the CoAl-LDH support through a facile in situ reduction between the oxidative Pd precursors and the reductive Co(II) in the support. The resultant CoAl-LDH/Pd composite catalyst showed excellent activities in cross-coupling reactions. In addition, the abundant Co(II) sites in the support can efficiently capture and regenerate leached Pd species during the reaction process, leading to excellent stability of the composite. These two features are desirable in organic synthesis, and may be used on a large scale for cross-coupling reactions with lower cost and easier operation.
引用
收藏
页码:12739 / 12745
页数:7
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