A time-of-flight, drift cell, quadrupole apparatus for ion mobility measurements

被引:29
作者
Weis, P [1 ]
Gilb, S [1 ]
Gerhardt, P [1 ]
Kappes, MM [1 ]
机构
[1] Univ Karlsruhe, Inst Phys Chem, D-76128 Karlsruhe, Germany
关键词
ion mobility measurements; time-of-flight mass spectrometer; ion mobility cell;
D O I
10.1016/S1387-3806(02)00554-7
中图分类号
O64 [物理化学(理论化学)、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号
070203 ; 070304 ; 081704 ; 1406 ;
摘要
We present an instrument that incorporates a combination of three different ion sources, an (upstream) time-of-flight mass spectrometer (TOFMS). an ion mobility cell and a quadrupole rnass filter. The key features of our setup are a TOFMS in front of the drift cell which allows the injection of short, intense, mass selected packets into the cell and the combination of different ion sources for increased versatility. Besides a detailed description of the experimental setup, we compare it to existing ion mobility configurations and show results on fullerenes, fullerene derivatives, large inorganic complexes and metal clusters. (C) 2002 Published by Elsevier Science B.V.
引用
收藏
页码:59 / 73
页数:15
相关论文
共 50 条
[1]   ENHANCED COALESCENCE UPON LASER-DESORPTION OF FULLERENE OXIDES [J].
BECK, RD ;
STOERMER, C ;
SCHULZ, C ;
MICHEL, R ;
WEIS, P ;
BRAUCHLE, G ;
KAPPES, MM .
JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (04) :3243-3249
[2]  
BOESL U, 1991, Patent No. 5032722
[3]  
BOESL U, 1993, Patent No. 3920566
[4]   Mass spectrometry: Recent advances and future directions [J].
Bowers, MT ;
Marshall, AG ;
McLafferty, FW .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (31) :12897-12910
[5]   Ab initio study of small gold clusters [J].
Bravo-Pérez, G ;
Garzón, IL ;
Novaro, O .
JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1999, 493 :225-231
[6]  
DAHL DA, SIMION 6 0 ID NAT EN
[7]   LASER PRODUCTION OF SUPERSONIC METAL CLUSTER BEAMS [J].
DIETZ, TG ;
DUNCAN, MA ;
POWERS, DE ;
SMALLEY, RE .
JOURNAL OF CHEMICAL PHYSICS, 1981, 74 (11) :6511-6512
[8]   High-resolution ion mobility measurements [J].
Dugourd, P ;
Hudgins, RR ;
Clemmer, DE ;
Jarrold, MF .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1997, 68 (02) :1122-1129
[9]   Superdiatomics and picosprings:: Cage-cage vibrations in C120O, C120O2, and in three isomers of C130O [J].
Eisler, HJ ;
Hennrich, FH ;
Werner, E ;
Hertwig, A ;
Stoermer, C ;
Kappes, MM .
JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (22) :3889-3897
[10]  
FENSKE D, 2000, ANGEW CHEM, V112, P1925