Selective Addition of P(O)-H Bonds to Alkynes Catalyzed by Transition Metals Immobilized on Polystyrene-bound Triphenylphosphine

被引：19

作者：

Chen, Tieqiao ^{[1
]}

Zhou, Yongbo ^{[1
]}

Guo, Cancheng ^{[1
]}

Han, Li-Biao ^{[2
]}

机构：

[1] Hunan Univ, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China

[2] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

CHEMISTRY LETTERS | 2013年 / 42卷 / 09期

关键词：

OXIDATIVE ADDITION; RHODIUM COMPLEXES; STEREOSELECTIVE HYDROPHOSPHINYLATION; DIPHENYLPHOSPHINE OXIDE; TERMINAL ALKYNES; HYDROPHOSPHORYLATION; HYDROFORMYLATION; REGIOSELECTIVITY; REVERSAL;

D O I：

10.1246/cl.130374

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Addition of P(O)-H bonds to alkynes catalyzed by transition metals (Rh, Pd, and Ni) immobilized on polystyrene-bound triphenylphosphine proceeded efficiently to afford high yields of the addition products with high regioselectivity. The immobilized catalysts were easily recovered from the reaction mixture via simple centrifugal separation and could be reused several times without severe deactivation.

引用

页码：1065 / 1067

页数：3

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