The synthesis and structural characterization of C3 symmetry "star-like" cluster [{Os3(μ-H)(CO)10}3{1,3,5-(μ-SCH2)3C6H3}]

被引：1

作者：

Sanchez-Cabrera, Gloria ^{[1
]}

Zuno-Cruz, Francisco J. ^{[1
]}

Lopez-Ruiz, Heraclio ^{[1
]}

Rosales-Hoz, Maria J. ^{[2
]}

Leyva, Marco A. ^{[2
]}

Rodriguez, Jose A. ^{[1
]}

机构：

[1] Univ Autonoma Estado Hidalgo, Ctr Invest Quim, Mineral De La Reforma 42184, Hgo, Mexico

[2] Inst Politecn Nacl, Ctr Invest & Estudios Avanzados, Dept Quim, Mexico City 07000, DF, Mexico

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2014年 / 751卷

关键词：

Osmium clusters; Thiolato complexes; C-3; symmetry; Crystal structure; Cyclic voltammetry; X-RAY STRUCTURES; TRIOSMIUM CLUSTER; 3-MU-CO-CONTAINING TRIANIONS; MOLECULAR-STRUCTURES; COMPLEXES; REACTIVITY; CRYSTAL; LIGANDS; RUTHENIUM; CARBONYL;

D O I：

10.1016/j.jorganchem.2013.08.035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cluster [{Os-3(mu-H)(CO)(10)}(3){1,3,5-(mu-SCH2)(3)C6H3}] has been prepared by the reaction of [Os-3(CO)(10)(NCMe)(2)] with 1,3,5-tris(mercaptomethyl) benzene under mild conditions; the cluster has been fully characterized by IR, NMR spectroscopy, HR-MS, X-ray crystallography and its redox behavior is also described. (C) 2013 Elsevier B.V. All rights reserved.

引用

页码：826 / 829

页数：4

共 32 条

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