pi-stacking of [Pt(2,2'-bipyridine)(ethylenediamine)](2+) as its hexafluorophosphate salt

被引:11
作者
Kato, M
Kosuge, C
Yano, S
Kimura, M
机构
[1] Department of Chemistry, Faculty of Science, Nara Women's University
关键词
D O I
10.1107/S0108270197002618
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The crystal structure of (2,2'-bipyridine-N,N')(ethylenediamine-N,N')platinum(II) bis(hexafluoraphosphate), [Pt(C2H8N2)(C10H8N2)](PF6)2, [Pt(bpy)(en)](PF6)(2), contains pi-bpy-stacked columns of platinum complex cations, The bpy ligands are stacked keeping van der Waals contacts although the crystal exhibits essentially the same (3) pi-pi* emission spectrum as that in dilute solution.
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页码:838 / 840
页数:3
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