Effect of precipitation and complexation on nanofiltration of strontium-containing nuclear wastewater

被引:49
作者
Hwang, ED
Lee, KW
Choo, KH
Choi, SJ [1 ]
Kim, SH
Yoon, CH
Lee, CH
机构
[1] Daegu Univ, Dept Architectural Civil & Environm Engn, Gyongsan 712714, Gyeongbuk, South Korea
[2] Kyungpook Natl Univ, Dept Environm Engn, Buk Gu, Taegu 702701, South Korea
[3] Seoul Natl Univ, Sch Chem Engn, Seoul 151742, South Korea
[4] Kyungnam Univ, Dept Environm Engn, Masan 631701, Gyeongnam, South Korea
关键词
nanofiltration; complexation; precipitation; strontium removal; fouling;
D O I
10.1016/S0011-9164(02)00554-4
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The performance of nanofiltration (NF) with the addition of poly (acrylic acid) (PAA) for treatment of strontium-bearing nuclear wastewater was investigated using different NF membranes at various pH levels and PAA/Sr ratios. Greater Sr removal at elevated pH was attributed to the formation of SrCO3(s) due to the dissolution of atmospheric CO2. A substantial improvement in Sr removal was achieved with the addition of PAA that can make complexes with strontium ions and then be rejected by NF membranes. However, a rapid decrease in feed solution pH aggravated the fouling of a NF membrane, possibly because of the formation and the sorption of associated forms of PAA at the membrane surface.
引用
收藏
页码:289 / 294
页数:6
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