Highly red-shifted NIR emission from a novel anthracene conjugated polymer backbone containing Pt(II) porphyrins

被引：18
作者：
Freeman, D. M. E. [1 ]
Minotto, A. [2 ]
Duffy, W. [3 ]
Fallon, K. J. [1 ]
McCulloch, I. [3 ]
Cacialli, F. [2 ]
Bronstein, H. [1 ]
机构：
[1] UCL, Dept Chem, London WC1H 0AJ, England
[2] UCL, London Ctr Nanotechnol, Dept Phys & Astron, London WC1E 6BT, England
[3] King Abdullah Univ Sci & Technol, SPERC, Thuwal 239556900, Saudi Arabia
来源：
POLYMER CHEMISTRY | 2016年 / 7卷 / 03期
关键词：
NEAR-INFRARED POLYMER; PHOTOPHYSICAL PROPERTIES; HIGH-PERFORMANCE; ENERGY-TRANSFER; GAP POLYMER; EFFICIENT; COMPLEXES; PHOSPHORESCENCE; ELECTROLUMINESCENCE; LUMINESCENCE;
D O I：
10.1039/c5py01473e
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We present the synthesis of a novel diphenylanthracene (DPA) based semiconducting polymer. The polymer is solubilised by alkoxy groups attached directly to a DPA monomer, meaning the choice of comonomer is not limited to exclusively highly solubilising moieties. Interestingly, the polymer shows a red-shifted elecroluminescence maximum (510 nm) when compared to its photoluminescence maximum (450 nm) which we attribute to excimer formation. The novel polymer was utilised as a host for a covalently- linked platinum(II) complexed porphyrin dopant. Emission from these polymers was observed in the NIR and again showed almost a 100 nm red shift from photoluminescence to electroluminescence. This work demonstrates that utilising highly aggregating host materials is an effective tool for inducing red-shifted emission in OLEDs.
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收藏
页码：722 / 730
页数：9
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