Ge-based interface passivation for atomic layer deposited La-doped ZrO2 on III-V compound (GaAs,In0.15Ga0.85As) substrates

被引:26
作者
Molle, Alessandro [1 ]
Brammertz, Guy [2 ]
Lamagna, Luca [1 ]
Fanciulli, Marco [1 ,3 ]
Meuris, Marc [2 ]
Spiga, Sabina [1 ]
机构
[1] INFM, CNR, Lab Nazl MDM, I-20041 Agrate Brianza Milano, Italy
[2] IMEC VZW, B-3001 Louvain, Belgium
[3] Univ Milano Bicocca, Dipartimento Sci Mat, Milan, Italy
关键词
atomic layer deposition; bonds (chemical); elemental semiconductors; germanium; lanthanum; passivation; semiconductor-insulator boundaries; surface composition; thin films; X-ray photoelectron spectra; zirconium compounds; OXIDATION;
D O I
10.1063/1.3182734
中图分类号
O59 [应用物理学];
学科分类号
摘要
La-doped ZrO2 thin films were grown by O-3-based atomic layer deposition on III-V (GaAs,In0.15Ga0.85As) substrates through direct growth and after intercalation of a Ge interface passivation layer. The interface composition was investigated by x-ray photoelectron spectroscopy, revealing a dramatic reduction of semiconductor-oxygen bonding upon Ge passivation. An improved electrical quality of the Ge-passivated interfaces due to the removal of Ga3+ bonding related traps is demonstrated by conductance measurements at various temperatures.
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页数:3
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共 24 条
[1]   Capacitance-Voltage Characterization of GaAs-Oxide Interfaces [J].
Brammertz, G. ;
Lin, H. C. ;
Martens, K. ;
Mercier, D. ;
Merckling, C. ;
Penaud, J. ;
Adelmann, C. ;
Sioncke, S. ;
Wang, W. E. ;
Caymax, M. ;
Meuris, M. ;
Heyns, M. .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2008, 155 (12) :H945-H950
[2]   The effect of dopants on the dielectric constant of HfO2 and ZrO2 from first principles [J].
Fischer, Dominik ;
Kersch, Alfred .
APPLIED PHYSICS LETTERS, 2008, 92 (01)
[3]   Scanning tunneling microscopy and spectroscopy of gallium oxide deposition and oxidation on GaAs(001)-c(2x8)/(2x4) [J].
Hale, MJ ;
Yi, SI ;
Sexton, JZ ;
Kummel, AC ;
Passlack, M .
JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (13) :6719-6728
[4]   Frequency dispersion reduction and bond conversion on n-type GaAs by in situ surface oxide removal and passivation [J].
Hinkle, C. L. ;
Sonnet, A. M. ;
Vogel, E. M. ;
McDonnell, S. ;
Hughes, G. J. ;
Milojevic, M. ;
Lee, B. ;
Aguirre-Tostado, F. S. ;
Choi, K. J. ;
Kim, J. ;
Wallace, R. M. .
APPLIED PHYSICS LETTERS, 2007, 91 (16)
[5]   Detection of Ga suboxides and their impact on III-V passivation and Fermi-level pinning [J].
Hinkle, C. L. ;
Milojevic, M. ;
Brennan, B. ;
Sonnet, A. M. ;
Aguirre-Tostado, F. S. ;
Hughes, G. J. ;
Vogel, E. M. ;
Wallace, R. M. .
APPLIED PHYSICS LETTERS, 2009, 94 (16)
[6]   Thermodynamic stability of Ga2O3(Gd2O3)/GaAs interface -: art. no. 191905 [J].
Huang, YL ;
Chang, P ;
Yang, ZK ;
Lee, YJ ;
Lee, HY ;
Liu, HJ ;
Kwo, J ;
Mannaerts, JP ;
Hong, M .
APPLIED PHYSICS LETTERS, 2005, 86 (19) :1-3
[7]   Depletion-mode GaAs metal-oxide-semiconductor field-effect transistor with HfO2 dielectric and germanium interfacial passivation layer [J].
Kim, Hyoung-Sub ;
Ok, Injo ;
Zhang, Manhong ;
Lee, T. ;
Zhu, F. ;
Yu, L. ;
Lee, Jack C. ;
Koveshnikov, S. ;
Tsai, W. ;
Tokranov, V. ;
Yakimov, M. ;
Oktyabrsky, S. .
APPLIED PHYSICS LETTERS, 2006, 89 (22)
[8]   Synchrotron radiation photoemission spectroscopic study of band offsets and interface self-cleaning by atomic layer deposited HfO2 on In0.53Ga0.47As and In0.52Al0.48As [J].
Kobayashi, M. ;
Chen, P. T. ;
Sun, Y. ;
Goel, N. ;
Majhi, P. ;
Garner, M. ;
Tsai, W. ;
Pianetta, P. ;
Nishi, Y. .
APPLIED PHYSICS LETTERS, 2008, 93 (18)
[9]   Thermal stability of electrical and structural properties of GaAs-based metal-oxide-semiconductor capacitors with an amorphous LaAlO3 gate oxide [J].
Koveshnikov, S. ;
Adamo, C. ;
Tokranov, V. ;
Yakimov, M. ;
Kambhampati, R. ;
Warusawithana, M. ;
Schlom, D. G. ;
Tsai, W. ;
Oktyabrsk, S. .
APPLIED PHYSICS LETTERS, 2008, 93 (01)
[10]   Ge-interface engineering with ozone oxidation for low interface-state density [J].
Kuzum, Duygu ;
Krishnamohan, Tejas ;
Pethe, Abhijit J. ;
Okyay, Ali K. ;
Oshima, Yasuhiro ;
Sun, Yun ;
McVittie, James P. ;
Pianetta, Piero A. ;
McIntyre, Paul C. ;
Saraswat, Krishna C. .
IEEE ELECTRON DEVICE LETTERS, 2008, 29 (04) :328-330