Microwave catalytic co-pyrolysis of chlorella vulgaris and oily sludge: Characteristics and bio-oil analysis

Co-pyrolysis of Chlorella vulgaris (CV) and Oily sludge (OS) under different mixing ratios were investigated by microwave furnace. NiO, activated carbon (AC) and their 1:1 compound (N1A1) with different additions (5%, 10%, 15% and 20%) were selected as microwave additives to study the effects on optimum mixing ratio of co -pyrolysis. The results indicated that mixing ratio of CV/OS = 1:1 (C1O1) was optimum for co-pyrolysis. Besides, 10% AC was optimal on improving pyrolysis characteristics of the C1O1 group. The most significant synergistic interaction of NiO and AC occurred in the 10% N1A1 group. Moreover, hydrocarbons in bio-oil of the C1O1 group increased by 31.84% compared with theoretical values, while nitrogenous, oxygenated compounds decreased by 74.18% and 19.01%. Addition of 10% N1A1 in the C1O1 group increased aliphatic hydrocarbons by 22.44%, and decreased nitrogenous, oxygenated compounds by 41.79% and 36.58%. Overall, 10% N1A1 was conducive for the C1O1 group to obtain high-quality bio-oil.