Tailoring Er3+ spectrally pure upconversion in bulk nano-glass-ceramics via lanthanide doping

被引：11

作者：

Chen, Daqin ^{[1
]}

Wan, Zhongyi ^{[1
]}

Zhou, Yang ^{[1
]}

Huang, Ping ^{[2
]}

Zhou, Xiangzhi ^{[3
]}

Yu, Yunlong ^{[4
]}

Zhong, Jiasong ^{[1
]}

Ding, Mingye ^{[1
]}

Ji, Zhenguo ^{[1
]}

机构：

[1] Hangzhou Dianzi Univ, Coll Mat & Environm Engn, Hangzhou 310018, Zhejiang, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[3] Hangzhou Guangrong Sci & Technol Co Ltd, Hangzhou 310018, Zhejiang, Peoples R China

[4] Fujian Jiangxia Univ, Coll Elect & Informat Sci, Fuzhou 350108, Fujian, Peoples R China

来源：

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY | 2016年 / 36卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Glass ceramic; NaLuF4; nanocrystal; Lanthanide; Upconversion; Optical materials; DOPED NAYF4; PHOTOCATALYTIC ACTIVITY; LUMINESCENCE; NANOCRYSTALS; EMISSION; TIO2; NANOPARTICLES; NANOMATERIALS; FLUORESCENCE; ENHANCEMENT;

D O I：

10.1016/j.jeurceramsoc.2015.11.007

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Lanthanide doped nano-glass-ceramics containing NaLuF4 particles were successfully prepared by the melt-quenching and subsequent glass crystallization. Elemental mappings in nanoscale and optical spectroscopy analyses evidenced the incorporation of lanthanide dopants into the NaLuE4 crystalline lattice. Impressively, the extra addition of specific Ce3+ or Tm3+ ions into Yb/Er doped nano-glass-ceramics induced the modification of Er3+ upconversion luminescent color from yellow to pure red, while the Pr3+ or Ho3+ doping was beneficial to the dominant green upconversion emission of Er3+. Ultimately, the impact of these dopants on the competition of radiation transitions from the two intermediate excited states of Er3+:H-2(11/2),S-4(3/2) (green-emitting) and Er3+:F-4(9/2) (red-emitting) was analyzed and discussed in detail. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：679 / 688

页数：10

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