Identification of Reaction Conditions That Can Reproducibly Lead to a Particular Vertex Geometry: Quest for a Robust and Reproducible Metal-Carboxylate Noncluster-type SBU

被引：41

作者：

Basu, Tannistha ^{[1
]}

Sparkes, Hazel A. ^{[2
]}

Bhunia, Manas Kumar ^{[1
]}

Mondal, Raju ^{[1
]}

机构：

[1] Indian Assoc Cultivat Sci, Dept Inorgan Chem, Kolkata 700032, India

[2] Univ Durham, Dept Chem, Durham DH1 3LE, England

来源：

CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 08期

关键词：

SECONDARY BUILDING UNITS; SILVER(I) COORDINATION NETWORKS; ORGANIC FRAMEWORKS; RETICULAR SYNTHESIS; POLYMERS; BIX=1,4-BIS(IMIDAZOL-1-YLMETHYL)BENZENE; CHEMISTRY; ANGSTROM; LIGANDS; DESIGN;

D O I：

10.1021/cg900195f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The present work reports the identification of a robust and reproducible metal-carboxylate noncluster-based secondary building unit (SBU) using flexible ligands, methylenebis(3,5-dimethylpyrazole). and homologous alkanedicarboxylic acids (HOOC(CH2)(n)-COOH). We have successfully synthesized a series of zinc(II) coordination polymers using a tailor-made SBU, designed with the proper utilization of the hydrogen bonds of a pyrazole-based ligand. We have identified a clear correlation between the type of auxiliary linker used and the vertex geometry that is present in the resultant network. This, in effect, can pave the way for the strategic control of the vertex geometry, which should enable Lis to design and predict the topology and dimensionality of a metal-organic framework.

引用

页码：3488 / 3496

页数：9

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