New macrocyclic ligands.: IX -: N-benzylated macrocycles incorporating O2N2-, O3N2- and O2N3-donor sets

被引：8

作者：

Kim, J ^{[1
]}

Lee, Y

Lee, SS

Lindoy, LF

Strixner, T

机构：

[1] Seonam Univ, Dept Chem, Namwon 590711, South Korea

[2] Gyeongsang Natl Univ, Dept Chem, Chinju 660701, South Korea

[3] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

[4] James Cook Univ N Queensland, Sch Biomed & Mol Sci, Townsville, Qld 4811, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1999年 / 52卷 / 11期

关键词：

D O I：

10.1071/CH99098

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The syntheses of N-benzylated macrocyclic ligands incorporating O2N2-, O3N2- and O2N3-donor sets, and ring sizes from 15- to 18-membered, is described. The new derivatives were obtained by benzylation of the previously reported parent macrocycles with benzyl bromide in acetonitrile containing suspended sodium carbonate or bicarbonate. The X-ray structure determination of a tribenzylated product containing a 17-membered, O2N3-donor macrocyclic ring is described.

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页码：1055 / 1059

页数：5

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