Thermochemical study of the trans- and cis-isomeric forms of 4-(4-methoxystyryl)pyridine N-oxide

被引:1
作者
Gubarev, Yu. A. [1 ]
Golubev, S. N. [1 ]
Lebedeva, N. Sh. [1 ]
V'yugin, A. I. [1 ]
Andreev, V. P. [2 ]
机构
[1] Russian Acad Sci, Krestov Inst Solut Chem, Ul Akad Skaya 1, Ivanovo 153040, Russia
[2] Petrozavodsk State Univ, Petrozavodsk, Kareliya, Russia
关键词
NONLINEAR-OPTICAL PROPERTIES; THERMAL CIS; AZOBENZENE; MOLECULES; PYRIDINE; STORAGE;
D O I
10.1134/S1070363217030392
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The trans and cis form of 4-(4-methoxystyryl)pyridine N-oxide were studied. The spectral characteristics of cis-4-(4-methoxystyryl)pyridine N-oxide were determined in acetonitrile. The melting and thermal decomposition processes of the trans and cisforms of 4-(4-methoxystyryl)pyridine N-oxide were studied by thermochemical methods. It was establish that the thermal decomposition of 4-(4-methoxystyryl)pyridine N-oxide begins with the cleavage of the bond between the pyridine and benzene rings.
引用
收藏
页码:619 / 623
页数:5
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