The reaction of peroxy radicals with OH radicals

被引：37

作者：

Fittschen, Christa ^{[1
]}

机构：

[1] Univ Lille, CNRS, UMR 8522, PC2A Physicochim Proc Combust & Atmosphere, F-59000 Lille, France

来源：

CHEMICAL PHYSICS LETTERS | 2019年 / 725卷

关键词：

LASER-INDUCED FLUORESCENCE; MASTER CHEMICAL MECHANISM; ABSORPTION CROSS-SECTIONS; RING-DOWN SPECTROSCOPY; RATE-CONSTANT; ATMOSPHERIC OXIDATION; CH3O2; RADICALS; METHYL PEROXY; IODINE OXIDE; HO2;

D O I：

10.1016/j.cplett.2019.04.002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction of peroxy radicals, RO2, with OH radicals has long been ignored to play any role in atmospheric chemistry. Recent experimental and modeling studies show however that these reactions are fast and can play a role in remote atmospheres with low NO concentrations when the major fate of peroxy radicals, its reaction with NO, slows down. The present article summarizes recent work on this class of reactions and its implications in different environments.

引用

页码：102 / 108

页数：7

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