Solvothermal Synthesis and Crystal Structure of K2CdSnS4

被引：0

作者：

Baiyin Meng-He ^{[1
,2
]}

Gang Gang ^{[1
]}

Naren Ji-Ru-Ga ^{[1
]}

机构：

[1] Inner Mongolia Normal Univ, Coll Chem & Environm Sci, Hohhot 010022, Peoples R China

[2] Key Lab Phys & Chem Funct Mat, Hohhot 010022, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2014年 / 30卷 / 02期

关键词：

solvothermal synthesis; crystal structure; quaternary thiostannate; optical property; OPEN-FRAMEWORK SULFIDE; FLUX SYNTHESIS; THIOSTANNATES; CHALCOGENIDES; RB; CS; ADAMANTANE; DISCRETE; IONS; MN2+;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Layered K2CdSnS4 (1) was synthesized solvothermally and characterized by X-ray single crystal diffraction. The crystals belong to the space group C2/c, with a=1.102 1(5) nm, b=1.103 0(5) nm, c=1.515 1(10) nm, alpha=90 degrees, P=100.416 (12)degrees, gamma=90 degrees, V=1.811 4 (17) nm(3), Z=8, D-e=3.209 g.cm(-3), M-r=437.60 mu=6.853 mm(-1), F(000)=1 600, lambda=0.071 073 nm, and the final R=0.104 2 and wR =0.200 8 for all observed reflections. The compound is comprised of sheets with adamantane-like [Cd2Sn2S10](8-) units. UV-Vis reflectance spectrum of compound 1 reveals that 1 is a semiconductor with a band gap of 2.2 eV. CCDC: 424763.

引用

页码：405 / 410

页数：6

共 46 条

[1] Magnetic behavior and Coulomb-lattice-gas ordering of Mn2+ and Sn4+ ions in K2MnSnS4 [J].

Albertelli, GD ;

Cowen, JA ;

Hoff, CN ;

Kaplan, TA ;

Mahanti, SD ;

Liao, JH ;

Kanatzidis, MG .

PHYSICAL REVIEW B, 1997, 55 (17) :11056-11059

[2] (NH3CH2CH2NH3)Ag2SnS4:: a quaternary sulfide-containing chiral layers [J].

An, YL ;

Menghe, B ;

Ye, L ;

Ji, M ;

Liu, X ;

Ning, GL .

INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (03) :301-303

[3] A solvothermal synthesis and characterization of a new open-framework K4Ag2Ge3S9•H2O [J].

An, YL ;

Ye, L ;

Ji, M ;

Liu, X ;

Menghe, B ;

Jia, CY .

JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (07) :2506-2510

[4] A solvothermal synthesis and the structure of K4Ag2Sn3S9•2KOH [J].

An, YL ;

Ji, M ;

Baiyin, M ;

Liu, X ;

Jia, CY ;

Wang, DH .

INORGANIC CHEMISTRY, 2003, 42 (14) :4248-4249

[5] K2Ag6Sn3S10:: A quaternary sulfide composed of silver sulfide layers pillared by zigzag chains ∞1[SnS3]2- [J].

Baiyin, M ;

An, YL ;

Liu, X ;

Ji, M ;

Jia, CY ;

Ning, GL .

INORGANIC CHEMISTRY, 2004, 43 (13) :3764-3765

[6]

Baiyin MH, 2011, CHEM RES CHINESE U, V27, P915

[7] A solvothermal synthesis and the structure of (NH4)2Ag6Sn3S10 [J].

BaiYin, MH ;

Ye, L ;

An, YL ;

Liu, X ;

Jia, CY ;

Ning, GL .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2005, 78 (07) :1283-1284

[8] New Three-Dimensional Thiostannates Composed of Linked Cu8S12 Clusters and the First Example of a Mixed-Metal Cu7SnS12 Cluster [J].

Behrens, Malte ;

Ordolff, Marie-Eve ;

Naether, Christian ;

Bensch, Wolfgang ;

Becker, Klaus-Dieter ;

Guillot-Deudon, Catherine ;

Lafond, Alain ;

Cody, Jason A. .

INORGANIC CHEMISTRY, 2010, 49 (18) :8305-8309

[9] Structurally characterized mesostructured hybrid surfactant-inorganic lamellar phases containing the adamantane [Ge4S10]4- anion:: Synthesis and properties [J].

Bonhomme, F ;

Kanatzidis, MG .

CHEMISTRY OF MATERIALS, 1998, 10 (04) :1153-1159

[10] Dimetal linked open frameworks: [(CH3)(4)N](2)(Ag-2,Cu-2)Ge4S10 [J].

Bowes, CL ;

Huynh, WU ;

Kirkby, SJ ;

Malek, A ;

Ozin, GA ;

Petrov, S ;

Twardowski, M ;

Young, D ;

Bedard, RL ;

Broach, R .

CHEMISTRY OF MATERIALS, 1996, 8 (08) :2147-2152

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