The Emergence of 2D MXenes Based Zn-Ion Batteries: Recent Development and Prospects

被引:121
作者
Javed, Muhammad Sufyan [1 ]
Mateen, Abdul [2 ,3 ]
Ali, Salamat [4 ]
Zhang, Xiaofeng [1 ]
Hussain, Iftikhar [5 ]
Imran, Muhammad [6 ]
Shah, Syed Shoaib Ahmad [7 ]
Han, Weihua [1 ]
机构
[1] Lanzhou Univ, Sch Phys Sci & Technol, Lanzhou 730000, Peoples R China
[2] Beijing Normal Univ, Dept Phys, Beijing 100084, Peoples R China
[3] Beijing Normal Univ, Beijing Key Lab Energy Convers & Storage Mat, Beijing 100084, Peoples R China
[4] Lanzhou Univ, Sch Mat & Energy, Lanzhou 730000, Peoples R China
[5] City Univ Hong Kong, Dept Mech Engn, Kowloon, 83 Tat Chee Ave, Hong Kong, Peoples R China
[6] King Khalid Univ, Fac Sci, Dept Chem, Abha 61413, Saudi Arabia
[7] Southwest Univ, Sch Mat & Energy, Minist Educ, Key Lab Luminescence Anal & Mol Sensing, Chongqing 400715, Peoples R China
基金
中国国家自然科学基金;
关键词
anodes; cathodes; flexible ZIBs (zinc-ion batteries); MXene-based materials; MXenes; zinc-ion batteries; 2-DIMENSIONAL TITANIUM CARBIDE; TRANSITION-METAL CARBIDES; TI3C2TX MXENE; LI-ION; CHARGE STORAGE; MATERIALS CHEMISTRY; ELECTRODE MATERIALS; THERMAL-STABILITY; ENERGY-STORAGE; GRAPHENE OXIDE;
D O I
10.1002/smll.202201989
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Rechargeable zinc-ion batteries (ZIBs) with exceptional theoretical capacity have garnered significant interest in large-scale electrochemical energy storage devices due to their low cost, abundant material, inherent safety, high specific energy, and ecofriendly nature. Metal carbides/nitrides, known as MXenes, have emerged as a large family of 2D transition metal carbides or carbonitrides with excellent properties, e.g., high electrical conductivity, large surface functional groups (e.g., -F, -O, and -OH), low energy barriers for the diffusion of electrolyte ions with wide interlayer spaces. After a decade of effort, significant development has been achieved in the synthesis, properties, and applications of MXenes. Thus, it has opened up various exciting opportunities to construct advanced MXene-based nanostructures for ZIBs with excellent specific energy and power. Herein, this review summarizes the advances across multiple synthesis routes, related properties, morphological and structural characteristics, and chemistries of MXenes for ZIBs. The recent development of MXene-based electrodes is introduced, and electrolytes for ZIBs are elucidated in detail. MXene-based rocking chair ZIBs, strategies to enhance the performance of MXene-based cathodes, suppress the dendrites in MXene-based anodes, and MXene-based flexible ZIBs are pointed out. A rational design and modification of the MXenes as well as the production of composites with metal oxides exhibits promise in solving issues and enhancing the electrochemical performance of ZIBs. Finally, the present challenges and future prospects for MXene-based ZIBs are discussed.
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页数:39
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