Tuning Interfacial Cu-O Atomic Structures for Enhanced Catalytic Applications

被引:21
作者
Sun, Shaodong [1 ]
Zhang, Xin [1 ]
Cui, Jie [1 ]
Yang, Qing [1 ]
Liang, Shuhua [1 ]
机构
[1] Xian Univ Technol, Sch Mat Sci & Engn, Shaanxi Prov Key Lab Elect Mat & Infiltrat Techno, Xian 710048, Shaanxi, Peoples R China
基金
中国博士后科学基金; 美国国家科学基金会;
关键词
atomic structure; catalysis; Cu2O; Cu; CuO; interface; METAL-ORGANIC FRAMEWORKS; HIGH-INDEX FACETS; THIN-FILMS; COMPOSITE; CUO/CU2O; SURFACE; HETEROJUNCTION; MICROCRYSTALS; PERFORMANCE; OXIDATION;
D O I
10.1002/asia.201900756
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Cu2O/CuOx (x=0, 1) nanocomposites with well-defined morphologies have been widely applied in catalytic reactions. However, people still understand less about tuning interfacial Cu-O atomic structures for enhanced catalytic applications, and a special review on this topic has not been reported so far. Herein, we summarize our understanding on tuning interfacial Cu-O atomic structures based on the literature, including the formation as well as evolution mechanism of Cu-O interfaces in Cu2O/CuO and Cu2O/Cu systems, and the improved performances in the fields of CO oxidation, NOx oxidation, photoelectrocatalysis, water gas shift reaction, photodegradation of organic dyes, hydrogen evolution, and photoreduction of CO2. Finally, we briefly propose several potential research directions.
引用
收藏
页码:2912 / 2924
页数:13
相关论文
共 61 条
[31]   Ppb H2S gas sensing characteristics of Cu2O/CuO sub-microspheres at low-temperature [J].
Meng, Fan-Na ;
Di, Xin-Peng ;
Dong, Hong-Wei ;
Zhang, Yue ;
Zhu, Chun-Ling ;
Li, Chunyan ;
Chen, Yu-Jin .
SENSORS AND ACTUATORS B-CHEMICAL, 2013, 182 :197-204
[32]   Water Gas Shift Catalysis [J].
Ratnasamy, Chandra ;
Wagner, Jon P. .
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING, 2009, 51 (03) :325-440
[33]   Facet-Controlled Synthetic Strategy of Cu2O-Based Crystals for Catalysis and Sensing [J].
Shang, Yang ;
Guo, Lin .
ADVANCED SCIENCE, 2015, 2 (10)
[34]   Cuprous oxide (Cu2O) crystals with tailored architectures: A comprehensive review on synthesis, fundamental properties, functional modifications and applications [J].
Sun, Shaodong ;
Zhang, Xiaojing ;
Yang, Qing ;
Liang, Shuhua ;
Zhang, Xiaozhe ;
Yang, Zhimao .
PROGRESS IN MATERIALS SCIENCE, 2018, 96 :111-173
[35]   Hollow CuxO (x=2, 1) micro/nanostructures: synthesis, fundamental properties and applications [J].
Sun, Shaodong ;
Yang, Qing ;
Liang, Shuhua ;
Yang, Zhimao .
CRYSTENGCOMM, 2017, 19 (42) :6225-6251
[36]   Recent advances in hybrid Cu2O-based heterogeneous nanostructures [J].
Sun, Shaodong .
NANOSCALE, 2015, 7 (25) :10850-10882
[37]   Cu2O-templated strategy for synthesis of definable hollow architectures [J].
Sun, Shaodong ;
Yang, Zhimao .
CHEMICAL COMMUNICATIONS, 2014, 50 (56) :7403-7415
[38]   Recent advances in tuning crystal facets of polyhedral cuprous oxide architectures [J].
Sun, Shaodong ;
Yang, Zhimao .
RSC ADVANCES, 2014, 4 (08) :3804-3822
[39]   The crystal-facet-dependent effect of polyhedral Cu2O microcrystals on photocatalytic activity [J].
Sun, Shaodong ;
Song, Xiaoping ;
Sun, Yuexia ;
Deng, Dongchu ;
Yang, Zhimao .
CATALYSIS SCIENCE & TECHNOLOGY, 2012, 2 (05) :925-930
[40]   Facet-selective growth of Cu-Cu2O heterogeneous architectures [J].
Sun, Shaodong ;
Kong, Chuncai ;
You, Hongjun ;
Song, Xiaoping ;
Ding, Bingjun ;
Yang, Zhimao .
CRYSTENGCOMM, 2012, 14 (01) :40-43