The synthesis of the first acetylenic silyl derivatives of 2-methylimidazole and benzimidazole

被引：5
|
作者：
Yarosh, N. O. [1 ]
Zhilitskaya, L. V. [1 ]
Shagun, L. G. [1 ]
Larina, L. I. [1 ]
Dorofeev, I. D. [1 ]
机构：
[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 10期
关键词：
1,3-bis(iodomethyl)tetramethyldisilylethyne; 2-methylimidazole; benzimidazole; alkylation; iodides; ONE-POT SYNTHESIS; IONIC LIQUID; IMIDAZOLE; ALKYLATION; SOLVENT; AGENTS;
D O I：
10.1134/S1070363215100151
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The earlier unknown acetylenic silyl iodides of linear and cyclic structure form in the reaction of 2-methylimidazole and benzimidazole with bis[dimethyl(iodomethyl)silyl]ethyne. The synthesized compounds are characterized by the data of elemental analysis, (1)De, D-13, N-15, Si-29 NMR, IR, Raman and UV spectroscopy.
引用
收藏
页码：2304 / 2308
页数：5
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