The synthesis of the first acetylenic silyl derivatives of 2-methylimidazole and benzimidazole

被引：5
|
作者：
Yarosh, N. O. [1 ]
Zhilitskaya, L. V. [1 ]
Shagun, L. G. [1 ]
Larina, L. I. [1 ]
Dorofeev, I. D. [1 ]
机构：
[1] Russian Acad Sci, Favorskii Irkutsk Inst Chem, Siberian Branch, Irkutsk 664033, Russia
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2015年 / 85卷 / 10期
关键词：
1,3-bis(iodomethyl)tetramethyldisilylethyne; 2-methylimidazole; benzimidazole; alkylation; iodides; ONE-POT SYNTHESIS; IONIC LIQUID; IMIDAZOLE; ALKYLATION; SOLVENT; AGENTS;
D O I：
10.1134/S1070363215100151
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The earlier unknown acetylenic silyl iodides of linear and cyclic structure form in the reaction of 2-methylimidazole and benzimidazole with bis[dimethyl(iodomethyl)silyl]ethyne. The synthesized compounds are characterized by the data of elemental analysis, (1)De, D-13, N-15, Si-29 NMR, IR, Raman and UV spectroscopy.
引用
收藏
页码：2304 / 2308
页数：5
相关论文
共 50 条
  • [1] The synthesis of the first acetylenic silyl derivatives of 2-methylimidazole and benzimidazole
    N. O. Yarosh
    L. V. Zhilitskaya
    L. G. Shagun
    L. I. Larina
    I. А. Dorofeev
    Russian Journal of General Chemistry, 2015, 85 : 2304 - 2308
  • [2] Alkylation of 2-methylimidazole with iodomethylsilanes
    Yarosh, N. O.
    Zhilitskaya, L. V.
    Shagun, L. G.
    Dorofeev, I. A.
    Larina, L. I.
    RUSSIAN JOURNAL OF ORGANIC CHEMISTRY, 2017, 53 (03) : 413 - 417
  • [3] REGULARITIES OF 2-METHYLIMIDAZOLE SYNTHESIS AND TECHNOLOGY OF ITS PRODUCTION
    Viktor, Malkov S.
    Oleg, Kotelnikov A.
    Vera, Tuguldurova P.
    Maria, Grabchenko V.
    TOMSK STATE UNIVERSITY JOURNAL, 2013, (367): : 200 - +
  • [4] Crystal and Molecular Structure Analysis of 2-Methylimidazole
    Hachula, Barbara
    Nowak, Maria
    Kusz, Joachim
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2010, 40 (03) : 201 - 206
  • [5] Switchable Dielectric Materials Based on 2-Methylimidazole
    Chen Li-Zhuang
    Sun Jun
    Ji Qin
    Pan Qi-Jian
    Huang Yao
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2017, 36 (02) : 329 - +
  • [6] COMPLEX FORMATION OF GOLD (I) WITH 2-METHYLIMIDAZOLE
    Bakhromi, Dilshod
    Safarmamadzoda, Safarmamad M.
    Muborakkadamov, Davron A.
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 2023, 66 (04): : 27 - 34
  • [7] The reaction of maleic and phthalic anhydrides with 2-methylimidazole
    Evtushenko Yu.M.
    Zaitsev B.E.
    Ivanov V.M.
    Gitis K.M.
    Evtushenko, Yu.M., 2000, Kluwer Academic/Plenum Publishers (36) : 1054 - 1057
  • [8] Crystal and Molecular Structure Analysis of 2-Methylimidazole
    Barbara Hachuła
    Maria Nowak
    Joachim Kusz
    Journal of Chemical Crystallography, 2010, 40 : 201 - 206
  • [9] Determination of 2-Methylimidazole and 4-Methylimidazole in Caramel Colors by Capillary Electrophoresis
    da Silveira Petruci, Joao Flavio
    Pereira, Elisabete Alves
    Cardoso, Arnaldo Alves
    JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2013, 61 (09) : 2263 - 2267
  • [10] Reaction of Imidazole and 2-Methylimidazole with Copper(II) Salts and Certain Acids
    Skorik, N. A.
    Il'ina, K. A.
    Kozik, V. V.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2021, 66 (11) : 1714 - 1721
12345