Radiation-induced nitration of organic compounds in aqueous solutions

被引：0
|
作者：
Ershov, B. G. [1 ]
Gordeev, A. V. [1 ]
Bykov, G. L. [1 ]
机构：
[1] Russian Acad Sci, Inst Phys Chem & Electrochem, Moscow 119991, Russia
来源：
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2009年 / 280卷 / 02期
关键词：
PULSE-RADIOLYSIS; ACETIC-ACID; DECOMPOSITION;
D O I：
10.1007/s10967-009-0504-x
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Radiation-induced nitration of organic compounds in aqueous solutions was studied. It was found that gamma-irradiation of solutions containing acetic and nitric acid and/or their salts gives nitromethane. Dependences of the product yield on the absorbed dose and the contents of components were established. The mechanism of radiation nitration involving radicals is discussed.
引用
收藏
页码：233 / 238
页数：6
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