On-Surface Fabrication of Small-Sized Nanoporous Graphene

被引:4
作者
Lu, Hui [1 ,2 ]
Wang, Haochen [1 ,2 ]
Wenlong, E. [1 ,2 ]
Dai, Dongxu [1 ]
Fan, Hongjun [1 ]
Ma, Zhibo [1 ]
Yang, Xueming [1 ,3 ]
机构
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, 457 Zhongshan Rd, Dalian 116023, Liaoning, Peoples R China
[2] Univ Chinese Acad Sci, 19 A Yuquan Rd, Beijing 100049, Peoples R China
[3] Southern Univ Sci & Technol, Dept Chem, 1088 Xueyuan Rd, Shenzhen 518055, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
POLYMERIZATION; NANORIBBONS; GROWTH; DRIVEN;
D O I
10.1021/acs.jpcc.9b01881
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
From the interplay of high-resolution scanning tunneling microscopy and density functional theory calculations, we have successfully obtained small-sized nanoporous graphene via a hierarchical reaction pathway involving two different kinds of reactions (Ullmann coupling and cyclodehydrogenation) of hexakis(4-bromopheny)benzene molecules (HEX-6Br) on Au(111).
引用
收藏
页码:14404 / 14407
页数:4
相关论文
共 46 条
  • [1] Molecules-Oligomers-Nanowires-Graphene Nanoribbons: A Bottom-Up Stepwise On-Surface Covalent Synthesis Preserving Long-Range Order
    Basagni, Andrea
    Sedona, Francesco
    Pignedoli, Carlo A.
    Cattelan, Mattia
    Nicolas, Louis
    Casarin, Maurizio
    Sambi, Mauro
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 137 (05) : 1802 - 1808
  • [2] Templating molecular adsorption using a covalent organic framework
    Blunt, Matthew O.
    Russell, James C.
    Champness, Neil R.
    Beton, Peter H.
    [J]. CHEMICAL COMMUNICATIONS, 2010, 46 (38) : 7157 - 7159
  • [3] Hierarchical On-Surface Synthesis of Graphene Nanoribbon Heterojunctions
    Bronner, Christopher
    Durr, Rebecca A.
    Rizzo, Daniel J.
    Lee, Yea-Lee
    Marangoni, Tomas
    Kalayjian, Alin Miksi
    Rodriguez, Henry
    Zhao, William
    Louie, Steven G.
    Fischer, Felix R.
    Crommie, Michael F.
    [J]. ACS NANO, 2018, 12 (03) : 2193 - 2200
  • [4] Atomically precise bottom-up fabrication of graphene nanoribbons
    Cai, Jinming
    Ruffieux, Pascal
    Jaafar, Rached
    Bieri, Marco
    Braun, Thomas
    Blankenburg, Stephan
    Muoth, Matthias
    Seitsonen, Ari P.
    Saleh, Moussa
    Feng, Xinliang
    Muellen, Klaus
    Fasel, Roman
    [J]. NATURE, 2010, 466 (7305) : 470 - 473
  • [5] Direct Formation of C-C Double-Bonded Structural Motifs by On-Surface Dehalogenative Homocoupling of gem-Dibromomethyl Molecules
    Cai, Liangliang
    Yu, Xin
    Liu, Mengxi
    Sun, Qiang
    Bao, Meiling
    Zha, Zeqi
    Pan, Jinliang
    Ma, Honghong
    Ju, Huanxin
    Hu, Shanwei
    Xu, Liang
    Zou, Jiacheng
    Yuan, Chunxue
    Jacob, Timo
    Bjork, Jonas
    Zhu, Junfa
    Qu, Xiaohui
    Xu, Wei
    [J]. ACS NANO, 2018, 12 (08) : 7959 - 7966
  • [6] Xanthine Quartets on Au(111)
    Chen, Chong
    Sang, Hongqian
    Ding, Pengcheng
    Sun, Ye
    Mura, Manuela
    Hu, Ying
    Kantorovich, Lev N.
    Besenbacher, Flemming
    Yu, Miao
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (01) : 54 - 57
  • [7] Combined Photoemission and Scanning Tunneling Microscopy Study of the Surface-Assisted Ullmann Coupling Reaction
    Chen, Min
    Xiao, Jie
    Steinrueck, Hans-Peter
    Wang, Shiyong
    Wang, Weihua
    Lin, Nian
    Hieringer, Wolfgang
    Gottfried, J. Michael
    [J]. JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (13) : 6820 - 6830
  • [8] Two-dimensional tessellation by molecular tiles constructed from halogen-halogen and halogen-metal networks
    Cheng, Fang
    Wu, Xue-Jun
    Hu, Zhixin
    Lu, Xuefeng
    Ding, Zijing
    Shao, Yan
    Xu, Hai
    Ji, Wei
    Wu, Jishan
    Loh, Kian Ping
    [J]. NATURE COMMUNICATIONS, 2018, 9
  • [9] Synthesis of Extended Graphdiyne Wires by Vicinal Surface Templating
    Cirera, Borja
    Zhang, Yi-Qi
    Bjork, Jonas
    Klyatskaya, Svetlana
    Chen, Zhi
    Ruben, Mario
    Barth, Johannes V.
    Klappenberger, Florian
    [J]. NANO LETTERS, 2014, 14 (04) : 1891 - 1897
  • [10] Substrate-Independent Growth of Atomically Precise Chiral Graphene Nanoribbons
    de Oteyza, Dimas G.
    Garcia-Lekue, Aran
    Vilas-Varela, Manuel
    Merino-Diez, Nestor
    Carbonell-Sanroma, Eduard
    Corso, Martina
    Vasseur, Guillaume
    Rogero, Celia
    Guitian, Enrique
    Ignacio Pascual, Jose
    Enrique Ortega, J.
    Wakayama, Yutaka
    Pena, Diego
    [J]. ACS NANO, 2016, 10 (09) : 9000 - 9008