Mapping the Electrical Conductivity of Poly(methyl methacrylate)/Carbon Black Composites Prior to and after Shear

被引：47
|
作者：
Liu, Xianhu [1 ,2 ]
Krueckel, Johannes [1 ]
Zheng, Guoqiang [2 ]
Schubert, Dirk W. [1 ]
机构：
[1] Univ Erlangen Nurnberg, Inst Polymer Mat, D-91058 Erlangen, Germany
[2] Zhengzhou Univ, Coll Mat Sci & Engn, Key Lab Mat Proc & Mold, Minist Educ, Zhengzhou 450002, Peoples R China
来源：
ACS APPLIED MATERIALS & INTERFACES | 2013年 / 5卷 / 18期
关键词：
carbon black; conductivity; mapping; polymer composites; shear stress; FILLED POLYMERS; CARBON-BLACK; TEMPERATURE; PERCOLATION;
D O I：
10.1021/am4031517
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
In this letter, the electrical conductivity of disklike poly(methyl methacrylate)/carbon black composite samples was investigated prior to and after a shear process. Novel electrical conductivity maps of the samples as a function of the position were obtained. It was found that the electrical conductivity after angular averaging of the static (nonsheared) sample is, as expected, independent of the radius. However, for the sheared sample, the electrical conductivity is decreasing from the center to the outer rim of the sample. This is attributed to the interplay of destruction and buildup effects of the applied linear shear stress on the agglomerate network.
引用
收藏
页码：8857 / 8860
页数：4
相关论文
共 50 条
  • [1] Viscoelastic and electrical behavior of poly(methyl methacrylate)/carbon black composites prior to and after annealing
    Pan, Yamin
    Liu, Xianhu
    Kaschta, Joachim
    Hao, Xiaoqiong
    Liu, Chuntai
    Schubert, Dirk W.
    POLYMER, 2017, 113 : 34 - 38
  • [2] Electrical conductivity behaviour of sheared poly(methyl methacrylate)/carbon black composites
    Liu, Xianhu
    Krueckel, Johannes
    Zheng, Guoqiang
    Schubert, Dirk W.
    COMPOSITES SCIENCE AND TECHNOLOGY, 2014, 100 : 99 - 104
  • [3] DC electrical conductivity of poly(methyl methacrylate)/carbon black composites at low temperatures
    Elimat, Z. M.
    Zihlif, A. M.
    Ragosta, G.
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2008, 19 (11) : 1035 - 1038
  • [4] DC electrical conductivity of poly(methyl methacrylate)/carbon black composites at low temperatures
    Z. M. Elimat
    A. M. Zihlif
    G. Ragosta
    Journal of Materials Science: Materials in Electronics, 2008, 19 : 1035 - 1038
  • [5] AC electrical conductivity of poly(methyl methacrylate)/carbon black composite
    Elimat, Z. M.
    JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2006, 39 (13) : 2824 - 2828
  • [6] Rheological and electrical behavior of poly(methyl methacrylate)/carbon black composites as investigated by creep recovery in shear
    Liu, Xianhu
    Pan, Yamin
    Zheng, Guoqiang
    Schubert, Dirk W.
    COMPOSITES SCIENCE AND TECHNOLOGY, 2016, 128 : 1 - 7
  • [7] Anomalous temperature dependence of the electrical conductivity of carbon-poly(methyl methacrylate) composites
    Alexander, MG
    MATERIALS RESEARCH BULLETIN, 1999, 34 (04) : 603 - 611
  • [8] Conductivity of Poly(methyl methacrylate)/Polystyrene/Carbon Black and Poly(ethyl methacrylate)/Polystyrene/Carbon Black Ternary Composite Films
    Hua-Gen Xu
    Mu-Chao Qu
    Ya-Min Pan
    Dirk W.Schubert
    Chinese Journal of Polymer Science, 2020, 38 (03) : 288 - 297
  • [9] Conductivity of Poly(methyl methacrylate)/Polystyrene/Carbon Black and Poly(ethyl methacrylate)/Polystyrene/Carbon Black Ternary Composite Films
    Xu, Hua-Gen
    Qu, Mu-Chao
    Pan, Ya-Min
    Schubert, Dirk W.
    CHINESE JOURNAL OF POLYMER SCIENCE, 2020, 38 (03) : 288 - 297
  • [10] Conductivity of Poly(methyl methacrylate)/Polystyrene/Carbon Black and Poly(ethyl methacrylate)/Polystyrene/Carbon Black Ternary Composite Films
    Hua-Gen Xu
    Mu-Chao Qu
    Ya-Min Pan
    Dirk W. Schubert
    Chinese Journal of Polymer Science, 2020, 38 : 288 - 297
12345