Pd-Catalyzed Hydrogen-Transfer Reactions from Alcohols to C=C, C=O, and C=N Bonds

被引：70
|
作者：
Muzart, Jacques [1 ]
机构：
[1] Univ Reims, Inst Chim Mol Reims, UMR CNRS 7312, UFR Sci Exactes & Naturelles, F-51687 Reims 2, France
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 2015卷 / 26期
关键词：
Homogeneous catalysis; Palladium; Hydrogen transfer; C-C coupling; C-O coupling; C-N coupling; Alcohols; ASYMMETRIC TRANSFER HYDROGENATION; SELECTIVE ALPHA-ALKYLATION; AEROBIC DEHYDROGENATION; N-ALKYLATION; PALLADIUM CATALYST; CARBONYL-COMPOUNDS; CONJUGATE REDUCTION; MECHANISTIC ASPECTS; TERMINAL ALKENES; ALLYLIC ALCOHOLS;
D O I：
10.1002/ejoc.201500401
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
This review covers Pd-catalyzed abstracting and borrowing hydrogen transfers from alcohols to C=C, C=O, and C=N bonds. An abstracting hydrogen transfer implies a reaction in which an alcohol serves only as a hydrogen atom source, whereas in a borrowing hydrogen transfer the alcohol is part of the final product. Both transfer types involve a palladium monohydride or palladium dihydride, and are implicated in a variety of useful and safe one-pot reactions such as the formation, with low quantities of waste material, of C-C, C-O, and C-N bonds. Plausible mechanisms are, as far as possible, provided.
引用
收藏
页码：5693 / 5707
页数：15
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