A green protocol for rapid and efficient conversion of epoxides to thiiranes using alumina immobilized thiourea at solvent-free conditions

被引：14

作者：

Eisavi, Ronak ^{[1
]}

Zeynizadeh, Behzad ^{[2
]}

机构：

[1] Payame Noor Univ, Dept Chem, POB 19395-3697, Tehran, Iran

[2] Urmia Univ, Fac Sci, Dept Chem, Orumiyeh 5756151818, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2016年 / 191卷 / 01期

关键词：

Alumina; epoxide; thiirane; thiourea; solvent-free; AMMONIUM THIOCYANATE; FACILE CONVERSION; OXIRANES; CATALYST; MILD; GEL; ALCOHOLS; ABSENCE; LIQUID; WATER;

D O I：

10.1080/10426507.2015.1085044

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Solvent-free conversion of various epoxides to the corresponding thiiranes was carried out successfully with alumina-immobilized thiourea at room temperature. The reactions were completed within 2-9min to give thiiranes with 83-98% yields. The utilized alumina can be reused for several times without losing its activity.

引用

页码：65 / 69

页数：5

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