A water-soluble cationic flocculant synthesized by dispersion polymerization in aqueous salts solution

被引:59
作者
Wang, Li Juan [1 ]
Wang, Jian-Ping [1 ]
Zhang, Shu-Juan [1 ]
Chen, Yong-Zhen [1 ]
Yuan, Shi-Jie [1 ]
Sheng, Guo-Ping [1 ]
Yu, Han-Qing [1 ]
机构
[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China
关键词
Cationic; Dispersion polymerization; Flocculant; Water-soluble; WASTE-WATER; COLOR REMOVAL; ACRYLAMIDE; COPOLYMERIZATION; CHLORIDE; METHACRYLATE; SUBSTANCES; COAGULANT; MONOMERS;
D O I
10.1016/j.seppur.2009.03.044
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
A water-soluble cationic flocculant, the copolymer of acrylamide (AM) and acryloylamino-2-hydroxypropyl trimethyl ammonium chloride (AMHP), has been synthesized through dispersion polymerization in aqueous ammonium sulfate ((NH4)(2)SO4) solution. The polymerization was initiated by potassium persulfate (KPS) using poly(2-methylacryloylxyethyl trimethyl ammonium chloride) (PDMC) as the stabilizer. The copolymer obtained was characterized using Fourier-transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy, colloidal titration and optical microscopy. Its flocculation properties were evaluated with 0.25 wt% kaolin suspensions using a standard jar test. The zeta potential of the supernates at different flocculant dosages was measured simultaneously. The results demonstrate the superiority of the copolymer over the commercial polyacrylamide as a flocculant. (C) 2009 Elsevier B.V. All rights reserved
引用
收藏
页码:331 / 335
页数:5
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