Highly sensitive and selective SO2 MOF sensor: the integration of MFM-300 MOF as a sensitive layer on a capacitive interdigitated electrode

被引:142
作者
Chernikova, Valeriya [1 ]
Yassine, Omar [2 ]
Shekhah, Osama [1 ]
Eddaoudi, Mohamed [1 ]
Salama, Khaled N. [2 ]
机构
[1] King Abdullah Univ Sci & Technol KAUST, Div Phys Sci & Engn, Adv Membranes & Porous Mat Ctr, Funct Mat Design,Discovery & Dev Res Grp FMD3, Thuwal 239556900, Saudi Arabia
[2] King Abdullah Univ Sci & Technol KAUST, Elect & Math Sci & Engn Div, Elect Engn Program, Sensors Lab,Comp, Thuwal 239556900, Saudi Arabia
关键词
METAL-ORGANIC FRAMEWORKS; SULFUR-DIOXIDE; THIN-FILMS; GAS SENSORS; CHEMICAL SENSORS; ROOM-TEMPERATURE; POROUS HOST; CO2; ADSORPTION; SURFACE;
D O I
10.1039/c7ta10538j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report on the fabrication of an advanced chemical capacitive sensor for the detection of sulfur dioxide (SO2) at roomtemperature. The sensing layer based on an indium metal-organic framework (MOF), namely MFM-300, is coated solvothermally on a functionalized capacitive interdigitated electrode. The fabricated sensor exhibits significant detection sensitivity to SO2 at concentrations down to 75 ppb, with the lower detection limit estimated to be around 5 ppb. The MFM-300 MOF sensor demonstrates highly desirable detection selectivity towards SO2 vs. CH4, CO2, NO2 and H-2, as well as an outstanding SO2 sensing stability.
引用
收藏
页码:5550 / 5554
页数:5
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