Formation of nanocrystalline and amorphous carbon by high fluence swift heavy ion irradiation of a plasma polymerized polyterpenol thin film precursor

被引：2

作者：

Grant, Daniel S. ^{[1
]}

Siegele, Rainer ^{[2
]}

Bazaka, Kateryna ^{[1
,3
]}

Jacob, Mohan V. ^{[1
]}

机构：

[1] James Cook Univ, Coll Sci & Engn, Townsville, Qld 4811, Australia

[2] Australian Nucl Sci & Technol Org, Inst Environm Res, Lucas Heights, NSW 2234, Australia

[3] Queensland Univ Technol, Sch Chem Phys & Mech Engn, Brisbane, Qld 4000, Australia

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2018年 / 135卷 / 29期

基金：

澳大利亚研究理事会;

关键词：

biopolymers and renewable polymers; irradiation; nanostructured polymers; CHEMICAL-VAPOR-DEPOSITION; RAMAN-SPECTROSCOPY; NANOSTRUCTURED CARBON; MECHANICAL-PROPERTIES; SURFACE MODIFICATION; HYDROGENATED CARBON; BEAM IRRADIATION; GRAPHENE; FABRICATION; GRAPHITE;

D O I：

10.1002/app.46498

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

This study aimed to produce graphitic-polymer nanocomposite thin films via the swift heavy ion irradiation of polyterpenol thin films synthesized from an environmentally sustainable precursor by radio-frequency plasma enhanced chemical vapor deposition. Atomic force microscopy and scanning electron microscopy revealed fluence-dependent surface restructuring of the thin films leading to the formation of interconnected island structures, with no discernible delamination from the underlying aluminum substrate. Raman spectroscopy confirmed the development of D and G peaks associated with graphitic materials, whilst Fourier transform infrared spectroscopy indicated retention of the plasma polymer's chemical functionalities (including hydroxyl groups) within the material after irradiation. Graphitic-polymer nanocomposite films prepared by this dry and solvent-free process have numerous potential applications in biological assay, organic electronics, and membrane technology. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46498.

引用

页数：7

共 70 条

[1] Carbon based materials for electronic bio-sensing [J].

Angione, Maria D. ;

Pilolli, Rosa ;

Cotrone, Serafina ;

Magliulo, Maria ;

Mallardi, Antonia ;

Palazzo, Gerardo ;

Sabbatini, Luigia ;

Fine, Daniel ;

Dodabalapur, Ananth ;

Cioffi, Nicola ;

Torsi, Luisa .

MATERIALS TODAY, 2011, 14 (09) :424-433

[2] Impact of nucleation of carbonaceous clusters on structural, electrical and optical properties of Cr+-implanted PMMA [J].

Arif, Shafaq ;

Rafique, M. Shahid ;

Saleemi, Farhat ;

Naab, Fabian ;

Toader, Ovidiu ;

Mahmood, Arshad ;

Aziz, Uzma .

APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 2016, 122 (09)

[3]

Balandin AA, 2011, NAT MATER, V10, P569, DOI [10.1038/nmat3064, 10.1038/NMAT3064]

[4] Swift heavy ion modification of polymers [J].

Balanzat, E ;

Betz, N ;

Bouffard, S .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1995, 105 (1-4) :46-54

[5] Anti-bacterial surfaces: natural agents, mechanisms of action, and plasma surface modification [J].

Bazaka, K. ;

Jacob, M. V. ;

Chrzanowski, W. ;

Ostrikov, K. .

RSC ADVANCES, 2015, 5 (60) :48739-48759

[6] Synthesis of radio frequency plasma polymerized non-synthetic Terpinen-4-ol thin films [J].

Bazaka, K. ;

Jacob, M. V. .

MATERIALS LETTERS, 2009, 63 (18-19) :1594-1597

[7] Sustainable Life Cycles of Natural-Precursor-Derived Nanocarbons [J].

Bazaka, Kateryna ;

Jacob, Mohan V. ;

Ostrikov, Kostya .

CHEMICAL REVIEWS, 2016, 116 (01) :163-214

[8] Efficient surface modification of biomaterial to prevent biofilm formation and the attachment of microorganisms [J].

Bazaka, Kateryna ;

Jacob, Mohan V. ;

Crawford, Russell J. ;

Ivanova, Elena P. .

APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 2012, 95 (02) :299-311

[9] Nanotribological and nanomechanical properties of plasma-polymerized polyterpenol thin films [J].

Bazaka, Kateryna ;

Jacob, Mohan V. .

JOURNAL OF MATERIALS RESEARCH, 2011, 26 (23) :2952-2961

[10] Do bacteria differentiate between degrees of nanoscale surface roughness? [J].

Bazaka, Kateryna ;

Crawford, Russell J. ;

Ivanova, Elena P. .

BIOTECHNOLOGY JOURNAL, 2011, 6 (09) :1103-1114

← 1 2 3 4 5 6 7 →