Zinc-catalyzed synthesis of 2-alkenylfurans via cross-coupling of enynones and diazo compounds

被引：61
作者：
Gonzalez, Jesus
Lopez, Luis A. [1 ]
Vicente, Ruben
机构：
[1] Univ Oviedo, Dept Quim Organ & Inorgan, Oviedo 33007, Spain
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 62期
关键词：
TRIFLUOROMETHYLATED ALKENES; TERMINAL ALKYNES; SOLAR-CELLS; CYCLOPROPANATION; GENERATION; IRON; CYCLIZATION; ALCOHOLS; HALIDES; KETONES;
D O I：
10.1039/c4cc03960b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Inexpensive, less-toxic ZnCl2 serves as the catalyst for selective cross-coupling of enynones and diazo compounds, an unprecedented reaction pathway for zinc carbenoids. A cascade sequence comprising formal cyclization/cross-coupling leads to a variety of 2-alkenylfurans.
引用
收藏
页码：8536 / 8538
页数：3
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