Specific functionalization on the surface of dendrimers

被引：69
|
作者：
Slany, M [1 ]
Caminade, AM [1 ]
Majoral, JP [1 ]
机构：
[1] CNRS,CHIM COORDINAT LAB,F-31077 TOULOUSE,FRANCE
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 50期
关键词：
D O I：
10.1016/S0040-4039(96)02123-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A specific monosubatitution on each P(X)(NH-CH2-CH=CH2)(2) terminal group (X = O, S) of phosphorus dendrimers is described from generation 1 to generation 7. This reaction allows to isolate compounds which possess simultaneously up to 192 phosphine, 192 N-H and 384 allyl groups. Preliminary experiments show that these functionalized dendrimers are able to complex transition metals such as iron and tungsten. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码：9053 / 9056
页数：4
相关论文
共 50 条
  • [1] The specific functionalization of cyclotriphosphazene for the synthesis of smart dendrimers
    Caminade, Anne-Marie
    Hameau, Aurelien
    Majoral, Jean-Pierre
    DALTON TRANSACTIONS, 2016, 45 (05) : 1810 - 1822
  • [2] Phosphorus containing dendrimers: synthesis and surface functionalization
    Majoral, JP
    Caminade, AM
    Kraemer, R
    ANALES DE QUIMICA-INTERNATIONAL EDITION, 1997, 93 (06): : 415 - 421
  • [3] Enhancement of Mechanophore Activation in Mechanochromic Dendrimers by Functionalization of Their Surface
    Watabe, Takuma
    Aoki, Daisuke
    Otsuka, Hideyuki
    MACROMOLECULES, 2021, 54 (04) : 1725 - 1731
  • [4] Thioacylation reactions for the surface functionalization of phosphorus-containing dendrimers
    Marchand, P
    Griffe, L
    Caminade, AM
    Majoral, JP
    Destarac, M
    Leising, F
    ORGANIC LETTERS, 2004, 6 (08) : 1309 - 1312
  • [5] Functionalization of phenylazomethine dendrimers
    Tetsuya Kambe
    Kimihisa Yamamoto
    Polymer Journal, 2022, 54 : 97 - 105
  • [6] Functionalization of phenylazomethine dendrimers
    Kambe, Tetsuya
    Yamamoto, Kimihisa
    POLYMER JOURNAL, 2022, 54 (02) : 97 - 105
  • [7] Prevention of Synaptic Alterations and Neurotoxic Effects of PAMAM Dendrimers by Surface Functionalization
    Vidal, Felipe
    Vasquez, Pilar
    Cayuman, Francisca R.
    Diaz, Carola
    Fuentealba, Jorge
    Aguayo, Luis G.
    Yevenes, Gonzalo E.
    Alderete, Joel
    Guzman, Leonardo
    NANOMATERIALS, 2018, 8 (01):
  • [8] Design and Synthesis of Dendrimers with Facile Surface Group Functionalization, and an Evaluation of Their Bactericidal Efficacy
    Ladd, Elizabeth
    Sheikhi, Amir
    Li, Na
    van de Ven, Theo G. M.
    Kakkar, Ashok
    MOLECULES, 2017, 22 (06)
  • [9] Specific Bifunctionalization on the Surface of Phosphorus Dendrimers Syntheses and Properties
    Petriccone, Massimo
    Laurent, Regis
    Turrin, Cedric-Olivier
    Sebastian, Rosa Maria
    Caminade, Anne-Marie
    ORGANICS, 2022, 3 (03): : 240 - 261
  • [10] Carbosilane dendrimers - Synthesis, functionalization, application
    Schlenk, C
    Frey, H
    MONATSHEFTE FUR CHEMIE, 1999, 130 (01): : 3 - 14
12345