A One-dimensional Pseudo-helical Coordination Polymer with 4,4′-(Hexafluoroisopropylidene)bis(benzoic acid)

被引：0
|
作者：
Zhao Wen-Na [1 ]
Han Lei [2 ]
机构：
[1] Zhejiang Univ, Ningbo Inst Technol, Key Lab Mol Design & Nutr Engn Ningbo, Ningbo 315100, Zhejiang, Peoples R China
[2] Ningbo Univ, Fac Chem Engn & Mat Sci, Ningbo 315211, Zhejiang, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2009年 / 28卷 / 03期
基金：
中国国家自然科学基金;
关键词：
coordination polymers; crystal structures; pseudo-helical chains; 4,4 '-(hexafluoroisopropylidene)bis(benzoic acid); DESIGN; MOF;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title complex [Zn-2(hfipbb)(2)(2,2 '-bPY)(2)](n) 1 has been hydrothermally synthesized from Zn(NO3)(2)center dot 6H(2)O, 4,4'-(hexafluoroisopropylidene)bis(berizoic acid) and 2,2'-bipyridine. Single-crystal X-ray analysis reveals that 1 presents a one-dimensional coordination polymer with pseudo-helical chain structure. Two Zn(II) atoms in an unsymmetrical unit of 1 adopt distorted octahedral and square-pyramidal coordination geometries, respectively. The packing of parallel chains gives a three-dimensional supramolecular network supported by pi ... pi stacking interactions. Crystal data: C54H32F12N4O8Zn2, M-r = 1223.58, monoclinic, space group P2(1)/c, a = 27.557(6), b = 16.751(3), c = 11.350(2) angstrom, beta = 99.21(3)degrees, V= 5171.5(18) angstrom(3), Z = 4, D-c = 1.572 g/cm(3), F(000) = 2464, mu = 1.030 mm(-1), the final R = 0.0552 and wR = 0.1070 for 6631 observed reflections (I > 2 sigma(I)).
引用
收藏
页码：343 / 347
页数：5
相关论文
共 50 条
  • [41] One-dimensional Europium-coordination polymer as luminescent sensor for highly selective and sensitive detection of 2,4,6-trinitrophenol
    Liu, Yanzhu
    Sun, Qingyan
    Zhou, Hongbo
    Gao, Hongyan
    Li, Dongping
    Li, Yongxiu
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2022, 264
  • [42] A chiral two-dimensional coordination polymer based on CuII and (S)-4,4′-bis(4-carboxyphenyl)-2,2′-bis(diphenylphosphinoyl)-1,1′-binaphthyl: Synthesis, structure, and magnetic and optical properties
    Lestari, Witri Wahyu
    Loennecke, Peter
    Streit, Huayna Cerqueira
    Schleife, Frederik
    Wickleder, Claudia
    Hey-Hawkins, Evamarie
    INORGANICA CHIMICA ACTA, 2014, 421 : 392 - 398
  • [43] Study on structure and properties of two metal coordination polymers prepared by 3,5-Bis (4-carboxy-phenoxy)benzoic acid
    Liu, Xin
    Zhao, Lun
    Zhao, Changjiang
    Meng, Lingshu
    Liu, Chang
    JOURNAL OF MOLECULAR STRUCTURE, 2019, 1188 : 238 - 243
  • [44] Synthesis, characterization and properties of lanthanide coordination polymers with 3,5-bis(4-carboxyphenylmethyloxy) benzoic acid
    Shi, Tian
    Chen, Ya-Guang
    Ren, Xiao-Yan
    NEW JOURNAL OF CHEMISTRY, 2017, 41 (19) : 11215 - 11224
  • [45] Anion Dependent Coordination Polymers of Different Copper Salts with Mixed Organic Ligands (bis(4-Nitrophenyl)phosphoric Acid and 4,4′-Bipyridine)
    Pattnaik, Archana Kumari
    Pedireddi, Venkateswara Rao
    CHEMISTRYSELECT, 2023, 8 (30):
  • [46] A New One-dimensional Complex Assembled by 4-Nitrobenzoic Acid and Bis(imidazol) Ligands: Syntheses, Structures and Theoretical Calculations
    Li Xiu-Mei
    Pan Ya-Ru
    Liu Bo
    Zhou Shi
    Chang Ying-Fei
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2019, 38 (05) : 783 - 790
  • [47] A 3D 2-fold interpenetrating Cu(II) coordination polymer based on 4,4′-oxybis(benzoic acid) and 1,3-bis(2-methyl-imidazol-1-yl) benzene exhibiting photocatalytic properties
    Qiao, Shan-Bao
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2021, 76 (3-4): : 237 - 241
  • [48] Syntheses and crystal structures of two Co(II) coordination polymers based on 4,6-bis(4-methylbenzoyl)isophthalic acid and 4,4′-bipyridine
    Tian, Dan
    Guan, Li
    Zhou, Yanhong
    Zhang, Hong
    JOURNAL OF COORDINATION CHEMISTRY, 2011, 64 (05) : 893 - 901
  • [49] Influence of different metal ions on the assembly, structures, and properties of two complexes based on the semi-rigid bis(pyridyl)-bis(amide) ligand and 4,4′-oxybis(benzoic acid)
    Lin, Hong-Yan
    Tian, Yuan
    Lin, Jia-Feng
    Wang, Xiang
    Liu, Guo-Cheng
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2018, 73 (06): : 359 - 368
  • [50] A 3D Nickel(II) Coordination Polymer with cds Nets Constructed from 3-Pyridin-4-yl-benzoic Acid
    Tang, Long
    Fu, Feng
    Gao, Loujun
    Wu, Yapan
    Liu, Quirui
    Gao, Xiaoming
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2011, 637 (05): : 608 - 612
12345