Engineering three-layer core-shell S-1/TS-1@dendritic-SiO2 supported Au catalysts towards improved performance for propene epoxidation with H2 and O2

被引:38
作者
Song, Zhaoning [1 ]
Yuan, Juncong [1 ]
Cai, Zhenping [2 ]
Lin, Dong [1 ]
Feng, Xiang [1 ]
Sheng, Nan [3 ]
Liu, Yibin [1 ]
Chen, Xiaobo [1 ]
Jin, Xin [1 ]
Chen, De [2 ]
Yang, Chaohe [1 ]
机构
[1] China Univ Petr, State Key Lab Heavy Oil Proc, Qingdao 266580, Peoples R China
[2] Norwegian Univ Sci & Technol, Dept Chem Engn, N-7491 Trondheim, Norway
[3] SINOPEC Qingdao Res Inst Safety Engn, State Key Lab Safety & Control Chem, 218 Yanansan Rd, Qingdao 266580, Peoples R China
关键词
Propene epoxidation; Selectivity; Core-shell; Dendritic SiO2 shell; TS-1; DIRECT PROPYLENE EPOXIDATION; GAS-PHASE EPOXIDATION; TITANIUM SILICALITE-1; ENHANCED STABILITY; AU/TS-1; CATALYST; GOLD CLUSTERS; ACTIVE-SITES; TS-1; NANOPARTICLES; OXIDATION;
D O I
10.1016/j.gee.2020.11.017
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The advocacy of green chemical industry has led to the development of highly efficient catalysts for direct gas-phase propene epoxidation with green, sustainable and simple essence. The S-1/TS-1@dendritic-SiO2 material with three-layer core-shell structure was developed and used as the support for Au catalysts, which showed simultaneously fantastic PO formation rate, PO selectivity and stability (over 100 h) for propene epoxidation with H-2 and O-2. It is found that silicalite-1 (S-1) core and the middle thin layer of TS-1 offer great mass transfer ability, which could be responsible for the excellent stability. The designed dendritic SiO2 shell covers part of the acid sites on the external surface of TS-1, inhibiting the side reactions and improving the PO selectivity. Furthermore, three kinds of SiO2 shell morphologies (i.e., dendritic, net, mesoporous shell) were designed, and relationship between shell morphology and catalytic performance was elucidated. The results in this paper harbour tremendous guiding significance for the design of highly efficient epoxidation catalysts. (C) 2020, Institute of Process Engineering, Chinese Academy of Sciences. Publishing services by Elsevier B.V. on behalf of KeAi Communications Co., Ltd.
引用
收藏
页码:473 / 483
页数:11
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