Crystal-Chemical Features of Diamonds Implanted with Helium Ions

被引:1
|
作者
Lopatin, O. N. [1 ]
Nikolaev, A. G. [1 ]
Valeev, V. F. [2 ]
Nuzhdin, V., I [2 ]
Khaibullin, R., I [2 ]
机构
[1] Kazan Volga Reg Fed Univ, Kremlevskaya 18, Kazan 420008, Russia
[2] RAS, Kazan Sci Ctr, Fed Res Ctr, Kazan EK Zavoisky Phys Tech Inst, Sibirskii Trakt 10-7, Kazan 420029, Russia
关键词
OPTICAL-PROPERTIES; COLORATION; SAPPHIRE; BERYL; CO;
D O I
10.1134/S1063774518030161
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
Implantation of high-energy helium ions into crystals of natural colorless diamonds colors them bright yellow, brown, or black, depending on the implantation dose. The nature of the induced fantasy color and crystal-chemical features of the implanted diamonds have been investigated by IR spectroscopy and Raman spectroscopy. It is established that the radiation effect of helium ions on the diamond crystal structure results in the transformation of nitrogen-vacancy centers in its bulk with the formation of new A-type color centers, as well as the formation of carbon nanoclusters with the sp(2) hybridization of bonds (which is typical of graphite) in black diamonds.
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页码:327 / 330
页数:4
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