Synthesis, Characterization, and Catalytic Application of Aluminum Anilido-Oxazolinate Complexes

被引：30

作者：

Chen, Chi-Tien ^{[1
]}

Weng, Han-Jade ^{[1
]}

Chen, Ming-Tsz ^{[1
]}

Huang, Chi-An ^{[1
]}

Peng, Kuo-Fu ^{[1
]}

机构：

[1] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2009年 / 14期

关键词：

Aluminum; Anilido-oxazolinate ligands; Ring-opening polymerization; Biodegradable polymers; RING-OPENING POLYMERIZATION; BIS-PHENOLATE LIGANDS; EPSILON-CAPROLACTONE; METAL-COMPLEXES; CYCLIC ESTERS; ZINC-COMPLEXES; EFFICIENT CATALYSTS; CYCLOHEXENE OXIDE; COPOLYMERIZATION; LACTIDE;

D O I：

10.1002/ejic.200900064

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A family of aluminum complexes containing anilido-oxazolinate ligands are described. Reactions of five anilido-oxazolinate ligand precursors, HNPh(TriMe)Oxa, HNPh(DiiPr)Oxa, HNPh(OMe)Oxa, HNPh(SMe)Oxa, or HNPhOxa, with 1 molar equiv. of AlMe(3) in toluene give the aluminum dimethyl complexes (NArOxa)AlMe(2) [Ar = 2,4,6-trimethylphenyl, (NPh(DiiPr)Oxa)AlMe(2) (1); Ar = 2,6-diisopropylphenyl, (NPh(DiiPr)Oxa)AlMe(2) (2); Ar = 2-methoxyphenyl, (NPh(OMe)Oxa)AlMe(2) (3); Ar = 2-methylthiophenyl, (NPh(SMe)Oxa)AlMe(2) (4); Ar = phenyl, (NPhOxa)AlMe(2) (5), respectively]. The molecular structures are reported for compounds 1-4. Their catalytic activities toward the ring-opening polymerization reactions of L-lactide or epsilon-caprolactone in the presence of BnOH are also under investigation. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)

引用

页码：2129 / 2135

页数：7

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