Lutidine/B(C6F5)3: At the Boundary of Classical and Frustrated Lewis Pair Reactivity

被引：288

作者：

Geier, Stephen J. ^{[1
]}

Stephan, Douglas W. ^{[1
]}

机构：

[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 10期

基金：

加拿大自然科学与工程研究理事会;

关键词：

HETEROLYTIC DIHYDROGEN ACTIVATION; FREE CATALYTIC-HYDROGENATION; METAL-FREE; BORANE; PHOSPHINES; CARBENE; IMINES; H-2;

D O I：

10.1021/ja900572x

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Classical Lewis acid-base adducts, previously thought to be unreactive, can provide access to the unique reactivity of frustrated Lewis pairs. This was demonstrated with a mixture of 2,6-lutidine and B(C6F5)(3) where an equilibrium affords the adduct and yet also effects the heterolytic activation of H-2 and the ring opening of THF.

引用

页码：3476 / +

页数：3

共 50 条

[41] Photo Lewis acid generators: photorelease of B(C6F5)3 and applications to catalysis
Khalimon, Andrey Y.
Shaw, Bryan K.
Marwitz, Adam J. V.
Piers, Warren E.
Blackwell, James M.
Parvez, Masood
DALTON TRANSACTIONS, 2015, 44 (41) : 18196 - 18206
[42] Adducts of the Lewis acid [B(C6F5)3] with transition metal oxo compounds
Barrado, G
Doerrer, L
Green, MLH
Leech, MA
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (07): : 1061 - 1066
[43] A Photo Lewis Acid Generator (PhLAG): Controlled Photorelease of B(C6F5)3
Khalimon, Andrey Y.
Piers, Warren E.
Blackwell, James M.
Michalak, David J.
Parvez, Masood
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (23) : 9601 - 9604
[44] N, P-Heterocyclic Germylene/B(C6F5)3 Adducts: A Lewis Pair with Multi-reactive Sites
Del Rio, Natalia
Lopez-Reyes, Morelia
Baceiredo, Antoine
Saffon-Merceron, Nathalie
Lutters, Dennis
Mueller, Thomas
Kato, Tsuyoshi
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (05) : 1365 - 1370
[45] Formation, structural characterization, and reactions of a unique cyclotrimeric vicinal Lewis pair containing (C6F5)2P-Lewis base and (C6F5) BH-Lewis acid components
Erdmann, Markus
Wiegand, Thomas
Blumenberg, Jonas
Eckert, Hellmut
Ren, Jinjun
Daniliuc, Constantin G.
Kehr, Gerald
Erker, Gerhard
DALTON TRANSACTIONS, 2014, 43 (40) : 15159 - 15169
[46] B(C6F5)3- and HB(C6F5)2-mediated transformations of isothiocyanates
Fischer, Malte
Schmidtmann, Marc
CHEMICAL COMMUNICATIONS, 2020, 56 (46) : 6205 - 6208
[47] Role of B(C6F5)3 in catalyst activation, anion formation, and as C6F5 transfer agent
Bochmann, M
Lancaster, SJ
Hannant, MD
Rodriguez, A
Schormann, M
Walker, DA
Woodman, TJ
PURE AND APPLIED CHEMISTRY, 2003, 75 (09) : 1183 - 1195
[48] Seven-Coordinate Group 6 Metal Hydrides Obtained by H2 Activation at B(C6F5)3 Adducts of N2 Complexes: Frustrated Lewis Pair-Type Reactivity of The B-N Linkage
Boegli, Marie-Christine
Coffinet, Anais
Bijani, Christian
Simonneau, Antoine
CHEMISTRY-AN ASIAN JOURNAL, 2024, 19 (17)
[49] Activation of H2 by frustrated Lewis pairs derived from mono- and bis-phosphinoferrocenes and B(C6F5)3
Ramos, Alberto
Lough, Alan J.
Stephan, Douglas W.
CHEMICAL COMMUNICATIONS, 2009, (09) : 1118 - 1120
[50] Reaction of five-membered zirconacycloallenoids with the strong Lewis acid B(C6F5)3
Bender, Georg
Daniliuc, Constantin G.
Wibbeling, Birgit
Kehr, Gerald
Erker, Gerhard
DALTON TRANSACTIONS, 2014, 43 (32) : 12210 - 12213

← 1 2 3 4 5 →