Probing solute-solvent interaction in 1-ethyl-3-methylimidazolium-based room temperature ionic liquids: A time-resolved fluorescence anisotropy study

Rotational diffusion of two organic solutes, coumarin153 (C153) and 4-aminophthalimide (AP) has been investigated in four ionic liquids (ILs), viz. 1-ethyl-3-methylimidazolium trifluoroacetate (EMIMTFA), 1-ethyl-3-methylimidazolium ethylsulfate (EMIMESU), 1-ethyl-3-methylimidazolium tetrafluoroborate (EMIMTFB) and 1-ethyl-3-methylimidazolium tetracyanoborate (EMIMTCB), as a function of temperature. Between the two probes, AP can act as hydrogen-bond-donor to the solvents having hydrogen bond acceptor ability. The results indicate that the rotational dynamics of C153 is mainly governed by the viscosity of the medium. On the other hand, the rotational motion of AP is found to be significantly hindered in the ILs depending on the nature of anions of the ILs. Rotational coupling constant values for AP in the ILs follow the order TFA > ESU > TCB > TFB. The slower rotational motion of AP in these ILs has been attributed to the specific hydrogen bonding interaction between AP and anions of ILs.