Structure and magnetic properties of a novel two-dimensional complex from 1,3,5-benzenetricarboxylate and neodymium(III) -: {[Nd(1,3,5-benzenetricarboxylate)(H2O)4]•H2O}n

被引：7
|
作者：
Wang, QL
Liang, M
Liao, DZ [1 ]
Yan, SP
Jiang, ZH
Cheng, P
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
[2] Peking Univ, State Key Lab Earth Mat Chem & Applicat, Beijing, Peoples R China
[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210008, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 04期
关键词：
neodymium; crystal structure; hydrogen bonds;
D O I：
10.1002/zaac.200300371
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A unique neodymium(III) complex, {[Nd(BTC)(H2O)(4)](H2O)-H-.}(n) (BTC = 1,3,5-benzenetricarboxylate), was obtained from the reaction between Nd(ClO4)(3)(.)xH(2)O and Na3BTC. Coordination bonds, hydrogen bonds, and pi-pi stacking form a supramolecular structure with a novel, two-dimensional framework. The temperature-dependent magnetic susceptibilities were analyzed by the Curie-Weiss law; the following values were found C = 1.32, theta = -18.3 K, respectively.
引用
收藏
页码：613 / 616
页数：4
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