Self-Organizing Maps and Learning Vector Quantization Networks As Tools to Identify Vegetable Oils

被引:12
作者
Torrecilla, Jose S. [1 ]
Rojo, Ester [1 ]
Oliet, Mercedes [1 ]
Dominguez, Juan C. [1 ]
Rodriguez, Francisco [1 ]
机构
[1] Univ Complutense Madrid, Fac Ciencias Quim, Dept Ingn Quim, E-28040 Madrid, Spain
关键词
Kohonen neural network; adulteration; competitive neural networks; extra virgin olive oil; seeds oil; ARTIFICIAL NEURAL-NETWORKS; OLIVE OIL; HAZELNUT OIL; PATTERN-RECOGNITION; FATTY-ACIDS; CLASSIFICATION; SPECTROSCOPY; ADULTERATION; VALIDATION; P-31;
D O I
10.1021/jf803520u
中图分类号
S [农业科学];
学科分类号
09 ;
摘要
Self-organizing map (SOM) and learning vector quantification network (LVQ) models have been explored for the identification of edible and vegetable oils and to detect adulteration of extra virgin olive oil (EVOO) using the most common chemicals in these oils, viz. saturated fatty (mainly palmitic and stearic acids), oleic and linoleic acids. The optimization and validation processes of the models have been carried out using bibliographical sources, that is, a database for developing learning process and internal validation, and six other different databases to perform their external validation. The model's performances were analyzed by the number of misclassifications. In the worst of the cases, the SOM and LVQ models are able to classify more than the 94% of samples and detect adulterations of EVOO with corn, soya, sunflower, and hazelnut oils when their oil concentrations are higher than 10, 5, 5, and 10%, respectively.
引用
收藏
页码:2763 / 2769
页数:7
相关论文
共 28 条
[1]  
[Anonymous], MATLAB USERS GUIDE V
[2]   Oil and fat classification by FT-Raman spectroscopy [J].
Baeten, V ;
Hourant, P ;
Morales, MT ;
Aparicio, R .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 1998, 46 (07) :2638-2646
[3]   Recognition of facial expressions using Gabor wavelets and learning vector quantization [J].
Bashyal, Shishir ;
Venayagamoorthy, Ganesh K. .
ENGINEERING APPLICATIONS OF ARTIFICIAL INTELLIGENCE, 2008, 21 (07) :1056-1064
[4]   Multivariate data analysis in classification of vegetable oils characterized by the content of fatty acids [J].
Brodnjak-Voncina, D ;
Kodba, ZC ;
Novic, M .
CHEMOMETRICS AND INTELLIGENT LABORATORY SYSTEMS, 2005, 75 (01) :31-43
[5]   The analysis of sensor array data with various pattern recognition techniques [J].
Ciosek, P ;
Wróblewski, W .
SENSORS AND ACTUATORS B-CHEMICAL, 2006, 114 (01) :85-93
[6]   Comparison of analytical methodologies based on 1H and 31P NMR spectroscopy with conventional methods of analysis for the determination of some olive oil constituents [J].
Dais, Photis ;
Spyros, Apostolos ;
Christophoridou, Stella ;
Hatzakis, Emmanuel ;
Fragaki, Georgia ;
Agiomyrgianaki, Alexia ;
Salivaras, Emmanuel ;
Siragakis, George ;
Daskalaki, Despina ;
Tasioula-Margari, Maria ;
Brenes, Manuel .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2007, 55 (03) :577-584
[7]   Detection of olive oil adulteration using principal component analysis applied on total and regio FA content [J].
Dourtoglou, VG ;
Dourtoglou, T ;
Antonopoulos, A ;
Stefanou, E ;
Lalas, S ;
Poulos, C .
JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY, 2003, 80 (03) :203-208
[8]  
*FAO, 1999, 210 CODEX STAN FAO
[9]   Geographical classification of crude oils by Kohonen self-organizing maps [J].
Fonseca, AM ;
Biscaya, JL ;
Aires-De-Sousa, J ;
Lobo, AM .
ANALYTICA CHIMICA ACTA, 2006, 556 (02) :374-382
[10]   Characterisation of vegetable oils by surface acoustic wave sensing electronic nose [J].
Gan, HL ;
Man, YBC ;
Tan, CP ;
NorAini, I ;
Nazimah, SAH .
FOOD CHEMISTRY, 2005, 89 (04) :507-518