Crystal structure of potassium nonafluorodibismuthate(III), K3Bi2F9

被引：0
作者：
Udovenko, AA
Gorbunova, YE
Davidovich, RL
Mikhailov, YN
Zemnukhova, LA
机构：
[1] Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
[2] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 117907, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2000年 / 26卷 / 02期
关键词：
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The crystal structure of a new potassium fluobismuthate(III), K3Bi2F9, was determined. The crystals are trigonal: a = 6.545, c = 19.333 Angstrom, rho(calcd) = 4.905 g/cm(3), Z = 3, space group R32. The structure is formed from the polymeric anionic [Bi2F9](n)(3n-) layers and K+ cations, which are united into a three-dimensional framework by electrostatic forces.
引用
收藏
页码：97 / 100
页数：4
相关论文
共 24 条
[1]   CRYSTAL STRUCTURE OF NH4BIF4 [J].
AURIVILLIUS, B ;
LINDBLOM, CI .
ACTA CHEMICA SCANDINAVICA, 1964, 18 (06) :1554-&
[2]   The structure of [(C2H5)(CH3)(2)(C6H5)N]3Bi2Cl9 at room temperature [J].
Blachnik, R ;
Jaschinski, B ;
Reuter, H .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1996, 211 (12) :911-915
[3]   CS3SB2I9 AND CS3BI2I9 WITH HEXAGONAL CS3CR2CL9 STRUCTURE TYPE [J].
CHABOT, B ;
PARTHE, E .
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (FEB) :645-648
[4]   The structure and phase transition of tris(n-propylammonium) enneachlorodiantimonate (III), (n-C3H7NH3)(3)Sb2Cl9 [J].
Ciapala, P ;
Zaleski, J ;
Bator, G ;
Jakubas, R ;
Pietraszko, A .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1996, 8 (12) :1957-1970
[5]  
DAVIDOVICH RL, 1988, KOORDINATS KHIM+, V14, P1011
[6]   PREPARATION, TEMPERATURE BEHAVIOR, AND CRYSTAL-STRUCTURE OF BIF3 [J].
GREIS, O ;
MARTINEZRIPOLL, M .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1977, 436 (DEC) :105-112
[7]   NONAHALOGENODIANTIMON(III)ATES - THEIR PREPARATION AND THE CRYSTAL-STRUCTURES OF [HPY]3[SB2CL9], [NME4]3[SB2BR9], AND [NME4]3[SB2BR3CL6] [J].
HALL, M ;
NUNN, M ;
BEGLEY, MJ ;
SOWERBY, DB .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1986, (06) :1231-1238
[8]  
HUND F, 1949, Z ANORGANISCHE ALLGE, V0258
[9]  
KALINCHENKO FV, 1983, ZH NEORG KHIM+, V28, P2354
[10]  
KALLE A, 1985, ACTA CRYSTALLOGR C, V41, P1027
123