Crystallographic evidence of theoretically novel anion-π interactions

被引：53
|
作者：
Casellas, Helene
Massera, Chiara
Buda, Francesco
Gamez, Patrick
Reedijk, Jan
机构：
[1] Leiden Univ, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands
[2] Univ Parma, Dipartimento Chim Gen & Inorgan, I-43100 Parma, Italy
来源：
NEW JOURNAL OF CHEMISTRY | 2006年 / 30卷 / 11期
关键词：
D O I：
10.1039/b608172j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of Cu(NO3)(2)center dot 3H(2)O with the multidentate ligand N,N',N '',N'''- tetrakis{2,4-bis (di-2-pyridylamino)-1,3,5-triazin-6-yl} triethylenetetramine (dpatta) in acetonitrile at high temperature and pressure results in the formation of the tetranuclear coordination compound [Cu-4(dpatta)(NO3)(4)](NO3)(4)center dot 12H(2)O ( 1), whose crystal structure exhibits remarkable anion-pi interactions which have been calculated, considering the unexpected position of the anion toward the aromatic ring.
引用
收藏
页码：1561 / 1566
页数：6
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