Superhydrophobic fabrics for oil-water separation through a diamond like carbon (DLC) coating

被引:175
作者
Cortese, Barbara [1 ,2 ]
Caschera, Daniela [3 ]
Federici, Fulvio [3 ]
Ingo, Gabriel M. [3 ]
Gigli, Giuseppe [1 ,4 ,5 ]
机构
[1] CNR NNL CNR NANO, Inst Nanosci, Natl Nanotechnol Lab, I-73100 Lecce, Italy
[2] Univ Roma La Sapienza, Dept Phys, I-00185 Rome, Italy
[3] ISMN CNR, Inst Study Nanostruct Mat, I-00016 Rome, Italy
[4] Univ Salento, Dept Math & Phys, Lecce, Italy
[5] Italian Inst Technol, Ctr Biomol Nanotechnol CNB, Lecce, Italy
关键词
SURFACE; DESIGN; THIN; NANOPARTICLES; WETTABILITY; ROUGHNESS; GRAPHENE; REMOVAL;
D O I
10.1039/c4ta00450g
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The recent oil spill in the Gulf of Mexico has already caused, and is continuing to cause, significant global environmental issues and has severely impacted people's lives and natural resources. The ramifications of oil spill accidents highlight the difficulty of achieving effective oil-water separation, and the consequences of these accidents are harsh and long-term. In this work, we describe a convenient approach to fabricate cotton textiles with a hydrophilic coating, showing both superhydrophobic and superoleophilic properties. The surfaces are successfully prepared by one-step growth of a diamond-like carbon film onto the textiles via plasma-enhanced chemical vapour deposition and exhibit highly controllable, energy-efficient oil-water separation with high separation efficiency. The results have important implications for oil-absorption dynamics while repelling water completely. The present work suggests encouraging applications to marine spilt oil cleanup and other water-oil separation systems.
引用
收藏
页码:6781 / 6789
页数:9
相关论文
共 42 条
[21]   Hydrophobic Nanocellulose Aerogels as Floating, Sustainable, Reusable, and Recyclable Oil Absorbents [J].
Korhonen, Juuso T. ;
Kettunen, Marjo ;
Ras, Robin H. A. ;
Ikkala, Olli .
ACS APPLIED MATERIALS & INTERFACES, 2011, 3 (06) :1813-1816
[22]   Applications of diamond-like carbon thin films [J].
Lettington, AH .
CARBON, 1998, 36 (5-6) :555-560
[23]   Superhydrophobic conjugated microporous polymers for separation and adsorption [J].
Li, An ;
Sun, Han-Xue ;
Tan, Da-Zhi ;
Fan, Wen-Jie ;
Wen, Shu-Hao ;
Qing, Xiao-Juan ;
Li, Gui-Xian ;
Li, Shi-You ;
Deng, Wei-Qiao .
ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (06) :2062-2065
[24]   The Cassie equation: How it is meant to be used [J].
Milne, A. J. B. ;
Amirfazli, A. .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2012, 170 (1-2) :48-55
[25]   Super-water-repellent fractal surfaces [J].
Onda, T ;
Shibuichi, S ;
Satoh, N ;
Tsujii, K .
LANGMUIR, 1996, 12 (09) :2125-2127
[26]   Mimicking the lotus effect: Influence of double roughness structures and slender pillars [J].
Patankar, NA .
LANGMUIR, 2004, 20 (19) :8209-8213
[27]   Drops at rest on a tilted plane [J].
Quere, D ;
Azzopardi, MJ ;
Delattre, L .
LANGMUIR, 1998, 14 (08) :2213-2216
[28]   IMPARTING WATER-REPELLENCY TO TEXTILES BY CHEMICAL METHODS - A REVIEW OF THE LITERATURE [J].
SCHUYTEN, HA ;
REID, JD ;
WEAVER, JW ;
FRICK, JG .
TEXTILE RESEARCH JOURNAL, 1948, 18 (07) :396-415
[29]   Extreme water repellency of nanostructured low-surface-energy non-woven fabrics [J].
Shin, Bongsu ;
Lee, Kwang-Ryeol ;
Moon, Myoung-Woon ;
Kim, Ho-Young .
SOFT MATTER, 2012, 8 (06) :1817-1823
[30]   Intrinsically superhydrophobic organosilica sol-gel foams [J].
Shirtcliffe, NJ ;
McHale, G ;
Newton, MI ;
Perry, CC .
LANGMUIR, 2003, 19 (14) :5626-5631