Two novel interpenetrated zinc(II) and cadmium(II) coordination polymers based on 4-imidazole-benzoate: Syntheses, crystal structures and properties

被引：27
作者：
Bai ZhengShuai [1 ]
Chen ShuiSheng [1 ]
Zhang ZhengHua [1 ]
Chen ManSheng [1 ]
Liu GuangXiang [1 ]
Sun WeiYin [1 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China
来源：
SCIENCE IN CHINA SERIES B-CHEMISTRY | 2009年 / 52卷 / 04期
关键词：
coordination polymer; interpenetration; crystal structure; photoluminescence property; METAL-ORGANIC FRAMEWORKS; NETWORKS; MANGANESE(II); LUMINESCENT; LIGANDS; COMPLEX; NETS;
D O I：
10.1007/s11426-009-0044-9
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two novel interpenetrated coordination polymers, [Zn(IBA)(2)] (n) (1) and {[Cd(IBA)(2)(H2O)]center dot 4H(2)O} (n) (2), have been synthesized by using 4-imidazole-benzoic acid (HIBA) as ligand under hydrothermal conditions. Complex 1 crystallizes in a chiral space group and has a two-fold interpenetrated 2D network structure with (4,4) topology, while complex 2 is a 3D porous dia network with four nets interpenetrating each other. The SHG activity of 1 and the photoluminescent property of 2 have been investigated.
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收藏
页码：459 / 464
页数：6
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