Magnetic Pt Catalyst for Selective Hydrogenation of Halonitrobenzenes

被引：35
作者：
Du, Weichen [1 ]
Xia, Shuixin [1 ]
Nie, Renfeng [1 ]
Hou, Zhaoyin [1 ]
机构：
[1] Zhejiang Univ, Dept Chem, Key Lab Appl Chem Zhejiang Prov, Hangzhou 310028, Zhejiang, Peoples R China
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2014年 / 53卷 / 12期
基金：
中国国家自然科学基金;
关键词：
LIQUID-PHASE HYDROGENATION; PLATINUM NANOPARTICLES; ORTHO-CHLORONITROBENZENE; OXIDE; CHLOROANILINE; REDUCTION; SUPPORT; SILICA; GROWTH; OXYGEN;
D O I：
10.1021/ie4041719
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Surfactant-free, H-2-reduced Pt NPs were successfully fabricated on the surface of Fe3O4. Characterizations disclosed that Pt NPs (3.1 nm on average) dispersed evenly on Fe3O4. This catalyst is extremely active and selective for hydrogenation of chloronitrobenzenes, convenient, and suitable for cyclic utilization. The study showed that the activity of Pt depended mainly on its particle size and that the Fe3O4 support is most favorable for this reaction.
引用
收藏
页码：4589 / 4594
页数：6
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共 35 条
  • [1] Shape-controlled synthesis of colloidal platinum nanoparticles
    Ahmadi, TS
    Wang, ZL
    Green, TC
    Henglein, A
    ElSayed, MA
    [J]. SCIENCE, 1996, 272 (5270) : 1924 - 1926
  • [2] Kinetics of the reduction of aromatic nitro compounds with hydrazine hydrate in the presence of an iron oxide hydroxide catalyst
    Benz, M
    Prins, R
    [J]. APPLIED CATALYSIS A-GENERAL, 1999, 183 (02) : 325 - 333
  • [3] A golden boost to an old reaction
    Blaser, Hans-Ulrich
    [J]. SCIENCE, 2006, 313 (5785) : 312 - 313
  • [4] Nanoshells Made Easy: Improving Au Layer Growth on Nanoparticle Surfaces
    Brinson, Bruce E.
    Lassiter, J. Britt
    Levin, Carly S.
    Bardhan, Rizia
    Mirin, Nikolay
    Halas, Naomi J.
    [J]. LANGMUIR, 2008, 24 (24) : 14166 - 14171
  • [5] One-pot synthesis of flowerlike Ni7S6 and its application in selective hydrogenation of chloronitrobenzene
    Cao, Feng
    Liu, Ruixia
    Zhou, Liang
    Song, ShuYan
    Lei, YongQian
    Shi, WeiDong
    Zhao, Fengyu
    Zhang, Hongjie
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (06) : 1078 - 1085
  • [6] Ag/SiO2:: A novel catalyst with high activity and selectivity for hydrogenation of chloronitrobenzenes
    Chen, YY
    Wang, CA
    Liu, HY
    Qiu, JS
    Bao, XH
    [J]. CHEMICAL COMMUNICATIONS, 2005, (42) : 5298 - 5300
  • [7] Janus Catalysts Direct Nanoparticle Reactivity
    Cole-Hamilton, David J.
    [J]. SCIENCE, 2010, 327 (5961) : 41 - 42
  • [8] Monodisperse magnetic single-crystal ferrite microspheres
    Deng, H
    Li, XL
    Peng, Q
    Wang, X
    Chen, JP
    Li, YD
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (18) : 2782 - 2785
  • [9] Chemoselective hydrogenation of halonitroaromatics over γ-Fe2O3-supported platinum nanoparticles: The role of the support on their catalytic activity and selectivity
    Evangelisti, Claudio
    Aronica, Laura Antonella
    Botavina, Maria
    Martra, Gianmario
    Battocchio, Chiara
    Polzonetti, Giovanni
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2013, 366 : 288 - 293
  • [10] SUPPORTED METAL-CLUSTERS - SYNTHESIS, STRUCTURE, AND CATALYSIS
    GATES, BC
    [J]. CHEMICAL REVIEWS, 1995, 95 (03) : 511 - 522
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