Preparation and Properties of MOF-derived Porous Carbon Nanosheets as Electrocatalyst for Oxygen Reduction Reaction

被引：1
作者：
Zhang, Jing [1 ,3 ]
Meng, Xiangzhi [2 ]
Zhao, Qiuping [2 ]
机构：
[1] Natl Nickel & Cobalt Adv Mat Engn Res Ctr, Lanzhou, Peoples R China
[2] Lanzhou Univ Technol, Sch Petrochem Technol, Lanzhou 730050, Peoples R China
[3] Lanzhou Jinchuan Technol Pk Co Ltd, Lanzhou 730101, Gansu, Peoples R China
来源：
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE | 2022年 / 17卷 / 09期
关键词：
Metal organic framework material; porous carbon nanosheets; double-metal; ORR; DOPED CARBON; NANOPARTICLES; PERFORMANCE; EVOLUTION;
D O I：
10.20964/2022.09.28
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
MOFs-derived nitrogen -doped porous carbon nanosheets Fe@Co/N@PCN were prepared by pyrolysis using Fe@Co/Zn-MOFs and g-C3N4 as precursor templates.The effects of metal doping on the catalytic activity of MOFs carriers were investigated by morphological structure and electrochemical performance characterization. It was found that the addition of bimetals not only increased the specific surface area of the catalysts, but also had a synergistic catalytic effect, resulting in a half-slope potential of 0.872 V vs. RHE in Fe@Co/N@PCN in 0.1 M KOH, and its ORR electrocatalytic activity, stability and methanol resistance were better than those of commercial Pt/C catalysts.
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页数：13
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