Acetonitrile-κN)dichlorobis(η5-pentamethylcyclopentadienyl)uranium(IV)

被引:2
作者
Maynadie, Jerome [1 ]
Berthet, Jean-Claude [1 ]
Thuery, Pierre [1 ]
Ephritikhine, Michel [1 ]
机构
[1] CEA Saclay, DSM, DRECAM, SCM,CNRS,URA 331, F-91191 Gif Sur Yvette, France
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2006年 / 62卷
关键词
D O I
10.1107/S1600536806040591
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [U(C10H15)(2)Cl-2(C2H3N)], is a bent uranium(IV) metallocene, in contrast with the recently reported linear ones that can be obtained in acetonitrile with anions less strongly coordinating than chloride. The two chloride ions in the equatorial plane are located next to each other, with the acetonitrile ligand on one side.
引用
收藏
页码:M2942 / M2943
页数:2
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