A New Electrochemical Sensor Based on Task-Specific Ionic Liquids-Modified Palm Shell Activated Carbon for the Determination of Mercury in Water Samples

被引：5

作者：

Abu Ismaiel, Ahmed ^{[1
]}

Aroua, Mohamed Kheireddine ^{[1
]}

Yusoff, Rozita ^{[1
]}

机构：

[1] Univ Malaya, Dept Chem Engn, Kuala Lumpur 50603, Malaysia

来源：

SENSORS | 2014年 / 14卷 / 07期

关键词：

palm shell activated carbon; ionic liquid; TOMATS; ion selective electrode; mercury; SELECTIVE ELECTRODE; PASTE ELECTRODE; POTENTIOMETRIC DETERMINATION; FLUORESCENCE SPECTROMETRY; ONLINE PRECONCENTRATION; FLOW;

D O I：

10.3390/s140713102

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In this study, a potentiometric sensor composed of palm shell activated carbon modified with trioctylmethylammonium thiosalicylate (TOMATS) was used for the potentiometric determination of mercury ions in water samples. The proposed potentiometric sensor has good operating characteristics towards Hg (II), including a relatively high selectivity; a Nernstian response to Hg (II) ions in a concentration range of 1.0 x 10(-9) to 1.0 x 10(-2) M, with a detection limit of 1 x 10(-10) M and a slope of 44.08 +/- 1.0 mV/decade; and a fast response time (similar to 5 s). No significant changes in electrode potential were observed when the pH was varied over the range of 3-9. Additionally, the proposed electrode was characterized by good selectivity towards Hg (II) and no significant interferences from other cationic or anionic species.

引用

页码：13102 / 13113

页数：12

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