Construction and photophysical properties of self-assembled linear porphyrin arrays

被引：50

作者：

Ogawa, Kazuya ^{[1
]}

Kobuke, Yoshiaki ^{[1
]}

机构：

[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300101, Japan

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS | 2006年 / 7卷 / 01期

关键词：

porphyrin; two-photon absorption; self-assembly; nonlinear optics;

D O I：

10.1016/j.jphotochemrev.2006.03.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A novel linear multi-porphyrin array consisting of meso-meso coupled bis(imidazolyl-zinc-porphyrin) was constructed by complementary coordination of imidazolyl to zinc. Although the giant polymer forms in nonpolar solvents, the molecular weight was controlled simply by adding appropriate amount of coordinating solvents or chain terminators. Oligomeric porphyrin arrays terminated with free base porphyrin exhibited 10 times larger third-order optical response than those terminated by zinc porphyrin. Extremely large two-photon absorption cross-section values were obtained by using bis(imidazolyl-zinc-porphyrin) linked through acetylenic bonds as the array-forming units. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：1 / 16

页数：16

共 72 条

[1] Novel heteroaromatic-based multi-branched dyes with enhanced two-photon absorption activity [J].

Abbotto, A ;

Beverina, L ;

Bozio, R ;

Facchetti, A ;

Ferrante, C ;

Pagani, GA ;

Pedron, D ;

Signorini, R .

CHEMICAL COMMUNICATIONS, 2003, (17) :2144-2145

[2] Novel heterocycle-based two-photon absorbing dyes [J].

Abbotto, A ;

Beverina, L ;

Bozio, R ;

Facchetti, A ;

Ferrante, C ;

Pagani, GA ;

Pedron, D ;

Signorini, R .

ORGANIC LETTERS, 2002, 4 (09) :1495-1498

[3] Comparative photophysics of [26]- and [28]hexaphyrins(1.1.1.1.1.1): Large two-photon absorption cross section of aromatic [26]hexaphyrins(1.1.1.1.1.1) [J].

Ahn, TK ;

Kwon, JH ;

Kim, DY ;

Cho, DW ;

Jeong, DH ;

Kim, SK ;

Suzuki, M ;

Shimizu, S ;

Osuka, A ;

Kim, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (37) :12856-12861

[4] Design of organic molecules with large two-photon absorption cross sections [J].

Albota, M ;

Beljonne, D ;

Brédas, JL ;

Ehrlich, JE ;

Fu, JY ;

Heikal, AA ;

Hess, SE ;

Kogej, T ;

Levin, MD ;

Marder, SR ;

McCord-Maughon, D ;

Perry, JW ;

Röckel, H ;

Rumi, M ;

Subramaniam, C ;

Webb, WW ;

Wu, XL ;

Xu, C .

SCIENCE, 1998, 281 (5383) :1653-1656

[5] Building molecular wires from the colours of life: conjugated porphyrin oligomers [J].

Anderson, HL .

CHEMICAL COMMUNICATIONS, 1999, (23) :2323-2330

[6] CONJUGATED PORPHYRIN LADDERS [J].

ANDERSON, HL .

INORGANIC CHEMISTRY, 1994, 33 (05) :972-981

[7] A systematic femtosecond study on the two-photon absorbing D-π-A molecules-π-bridge nitrogen insertion and strength of the donor and acceptor groups [J].

Antonov, L ;

Kamada, K ;

Ohta, K ;

Kamounah, FS .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (06) :1193-1197

[8] Giant meso-meso-linked porphyrin arrays of micrometer molecular length and their fabrication [J].

Aratani, N ;

Takagi, A ;

Yanagawa, Y ;

Matsumoto, T ;

Kawai, T ;

Yoon, ZS ;

Kim, D ;

Osuka, A .

CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (11) :3389-3404

[9] The third-order NLO properties of D-π-A molecules with changing a primary amino group into pyrrole [J].

Audebert, P ;

Kamada, K ;

Matsunaga, K ;

Ohta, K .

CHEMICAL PHYSICS LETTERS, 2003, 367 (1-2) :62-71

[10]

Bhawalkar J D, 1997, J Clin Laser Med Surg, V15, P201

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