A quick and easy synthesis of fluorescent iron oxide nanoparticles featuring a luminescent carbonaceous coating via in situ pyrolysis of organosilane ligands
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作者:
Worden, M.
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Kent State Univ, Dept Chem & Biochem, Kent, OH 44240 USAKent State Univ, Dept Chem & Biochem, Kent, OH 44240 USA
Worden, M.
[1
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Bergquist, L.
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Kent State Univ, Inst Liquid Crystal, Chem Phys Interdisciplinary Program, Kent, OH 44240 USAKent State Univ, Dept Chem & Biochem, Kent, OH 44240 USA
Bergquist, L.
[2
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Hegmann, T.
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Kent State Univ, Dept Chem & Biochem, Kent, OH 44240 USA
Kent State Univ, Inst Liquid Crystal, Chem Phys Interdisciplinary Program, Kent, OH 44240 USAKent State Univ, Dept Chem & Biochem, Kent, OH 44240 USA
Hegmann, T.
[1
,2
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机构:
[1] Kent State Univ, Dept Chem & Biochem, Kent, OH 44240 USA
[2] Kent State Univ, Inst Liquid Crystal, Chem Phys Interdisciplinary Program, Kent, OH 44240 USA
We report a simple, two-step method for making magnetic, photoluminescent iron oxide ( magnetite) core/carbonaceous shell nanoparticles emitting blue light. The core-shell nanoparticles are created by an aqueous synthesis and functionalized in situ with three different organosilanes. Pyrolysis of the organosilane ligand shell at 200 degrees C yields water-dispersible core-shell particles visibly fluorescing under UV light.